CdSe Nanoparticles Synergized with 2D TiCT MXene as the Dual-Function Composite for Enhanced K Ion Storage and Water Splitting.

Developing high-performance materials for energy storage and water splitting remains a significant challenge in energy research. Metal selenides, such as CdSe, exhibit excellent electrical conductivity and electrochemical activity, but they tend to form aggregates. Two-dimensional (2D) TiCT MXene has good stability and conductivity but is limited by its low capacitance and electrocatalytic performance. To address these issues, CdSe@TiCT composites were synthesized by a two-step large-scale hydrothermal method, where CdSe nanoparticles were uniformly grown on TiCT MXene nanosheets. The composites significantly enhance the specific capacity, ion mobility, cycling stability, and catalysis activity due to the synergistic effect between TiCT and CdSe nanoparticles. In a three-electrode system, the composites achieve a specific capacitance of 1847 F g at 0.125 mA cm and retain 89.2% of their capacitance after 10 000 cycles, demonstrating superior electrochemical properties compared to those of CdSe- or TiCT-based electrodes. The asymmetric supercapacitor (ASC) with CdSe@TiCT as the positive electrode and activated carbon (AC) as the negative electrode has a specific capacitance of 219.1 F g, a capacity retention of 88.1% after 5000 cycles, and an energy density of 45.8 W kg. This research also analyzes the reasons for the performance enhancement from the perspective of density of states theory. Furthermore, the CdSe@TiCT composite shows catalytic potential for water splitting, with overpotentials of 201 mV for the hydrogen evolution reaction (HER) and 276 mV for the oxygen evolution reaction (OER). These results suggest that 2D MXene-based CdSe is a promising candidate for energy storage and water splitting.