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偶氮苯的电化学及其储能潜力。

Electrochemistry of Azobenzenes and Its Potential for Energy Storage.

作者信息

Schatz Dominic, Wegner Hermann A

机构信息

Institute of Organic Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17, 35392 Gießen, Germany.

Center of Materials Research (ZfM/LaMa), Justus Liebig University, Heinrich-Buff-Ring 16, 35392 Gießen, Germany.

出版信息

J Org Chem. 2025 Apr 25;90(16):5336-5342. doi: 10.1021/acs.joc.5c00315. Epub 2025 Apr 14.

Abstract

Azobenzenes are promising materials for energy storage due to their reversible photoisomerization and redox properties. Given the critical role of redox behavior in the latter application, an investigation of their redox processes is essential. We propose a classification of azobenzenes into two categories: -type and -type, based on the mechanism of their oxidation. -type compounds have been extensively studied due to their reversible reduction. -type compounds exhibit oxidative and reductive versatility, making them promising for further research in energy storage.

摘要

偶氮苯因其可逆的光异构化和氧化还原特性,是用于能量存储的有前景的材料。鉴于氧化还原行为在后者应用中的关键作用,对其氧化还原过程进行研究至关重要。我们基于偶氮苯的氧化机制,将其分为两类:-型和-型。-型化合物因其可逆还原已得到广泛研究。-型化合物表现出氧化和还原的多功能性,使其在能量存储方面有进一步研究的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1bde/12038846/9eecaf4e529a/jo5c00315_0001.jpg

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