The effect of moisture on the adsorption of chloroform by activated carbon.

The effect of moisture on the ability of a granular activated carbon to adsorb chloroform vapor from a flowing airstream was studied under three test conditions: (1) chloroform and water vapor were introduced concurrently into a dry carbon bed; (2) dry chloroform was introduced into a humidified carbon bed; (3) humidified chloroform was introduced into a carbon bed at the same relative humidity. The criterion for bed performance was the time when the downstream chloroform concentration was 1% of that in the inlet stream. Chloroform concentration was essentially constant at 108 +/- 2 micrograms/cm3; relative humidities (RH) varied from 0 to 97%. No RH effect on the adsorption of chloroform by the carbon was observed in test (1); tests (2) and (3) showed monotonic decreases in chloroform adsorption for RH greater than 40%. These results indicated that, for a dry carbon bed, the 1% breakthrough time for chloroform adsorbed from atmospheres of RH from 13% to 95% was essentially the same as that when RH = 0%. For humidified carbon beds, no change in 1% breakthrough time for chloroform was observed until RH was greater than 40%.