Ahmad Nafis, Kanjariya Prakash, Priya G Padma, Kumar Anjan, Thakur Rishabh, Sharma Rsk, Kumari Mukesh, Kaur Sharnjeet, Mishra Manoj Kumar
Department of Physics, College of Science, King Khalid University, Abha 61413, Saudi Arabia.
Marwadi University Research Center, Department of Physics, Faculty of Science Marwadi University, Rajkot 360003, Gujarat, India.
ACS Omega. 2025 Apr 1;10(14):13780-13796. doi: 10.1021/acsomega.4c11667. eCollection 2025 Apr 15.
Perovskite oxide-based materials (ABO) have gained much attention as promising candidates for advanced gas-sensing applications due to their versatile structures, tunable properties, and excellent stability. This review discusses recent developments in the synthesis, structural optimization, and functionalization of perovskites to enhance their gas-sensing performance. Strategies such as doping, creating oxygen vacancies, tuning morphology, and forming heterojunctions have significantly improved their sensitivity, selectivity, response, and recovery times. Specific advances include the incorporation of nanostructures, porous morphologies, and catalytic elements, which have optimized the adsorption and desorption processes for various target gases, including volatile organic compounds, NO, and CO. Mechanistic insights into the role of oxygen vacancies, surface defects, and charge carrier dynamics are also addressed. These developments position perovskite materials as important components in next-generation gas sensors for environmental monitoring and industrial applications.
基于钙钛矿氧化物的材料(ABO)因其多样的结构、可调节的性能和出色的稳定性,作为先进气体传感应用的有前途候选材料而备受关注。本文综述了钙钛矿在合成、结构优化和功能化方面的最新进展,以提高其气体传感性能。诸如掺杂、创造氧空位、调整形貌和形成异质结等策略显著改善了它们的灵敏度、选择性、响应和恢复时间。具体进展包括纳入纳米结构、多孔形貌和催化元素,这些优化了对各种目标气体(包括挥发性有机化合物、NO和CO)的吸附和解吸过程。还讨论了关于氧空位、表面缺陷和电荷载流子动力学作用的机理见解。这些进展使钙钛矿材料成为用于环境监测和工业应用的下一代气体传感器的重要组件。