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用于挥发性有机化合物(VOC)气体传感的钙钛矿材料的最新进展

Recent Progress on Perovskite Materials for VOC Gas Sensing.

作者信息

Singh Paulomi, Bansal Nitin Kumar, Dey Sutapa, Singh Rajendra, Singh Trilok

机构信息

School of Interdisciplinary Research, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India.

Semiconductor Thin Films and Emerging Photovoltaic Laboratory, Department of Energy Science and Engineering, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India.

出版信息

Langmuir. 2024 Oct 22;40(42):21931-21956. doi: 10.1021/acs.langmuir.4c02089. Epub 2024 Oct 8.

Abstract

Volatile organic compound (VOC) gases are highly hazardous to human health, and their presence in the human breath plays an indispensable role for the early diagnosis of various diseases (cancer, renal failure, etc.). In recent times, perovskite materials have shown notable performance in the detection of VOC gases with high accuracy, fast response, recovery time, selectivity, and sensitivity, owing to their unique crystallographic structures and excellent optoelectronic properties. In this Review, we look at recent reports on perovskite-based sensors and their sensing performance toward VOC gases. Here, we focus on the sensing mechanisms of two types of perovskite materials, metal halide and metal oxide perovskites, and explain the differences in their crystal structures. We also discuss the common preparation methods used by researchers for the synthesis of these perovskite materials. Further, we elucidate various important factors influencing the sensing performance of perovskite-based sensors, such as doping, defects, morphology, temperature, humidity, and light. We conclude with the future prospects and challenges related to these perovskite-based sensors toward the detection of VOC gases.

摘要

挥发性有机化合物(VOC)气体对人体健康危害极大,其在人体呼出气体中的存在对于各种疾病(癌症、肾衰竭等)的早期诊断起着不可或缺的作用。近年来,钙钛矿材料因其独特的晶体结构和优异的光电性能,在高精度、快速响应、恢复时间、选择性和灵敏度检测VOC气体方面表现出显著性能。在本综述中,我们审视了近期关于钙钛矿基传感器及其对VOC气体传感性能的报道。在此,我们聚焦于两种钙钛矿材料——金属卤化物和金属氧化物钙钛矿的传感机制,并解释它们晶体结构的差异。我们还讨论了研究人员用于合成这些钙钛矿材料的常见制备方法。此外,我们阐明了影响钙钛矿基传感器传感性能的各种重要因素,如掺杂、缺陷、形态、温度、湿度和光照。我们最后总结了这些钙钛矿基传感器在检测VOC气体方面的未来前景和挑战。

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