双齿（P^N）金（III）-叠氮配合物：合成与还原消除研究。
Bidentate (P^N) Au(III)-azide complexes: synthesis and reductive elimination studies.
作者信息
Patil Nitin T
机构信息
Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Bhopal Bypass Road, Bhauri, Bhopal - 462 066, India.
出版信息
Chem Commun (Camb). 2025 May 13;61(40):7297-7300. doi: 10.1039/d5cc01179e.
Herein, we report the synthesis and characterization of novel (P^N) aryl Au(III)-azide complexes. The reductive elimination from these Au(III) complexes to forge C(sp)-N bonds has also been demonstrated. Considering the feasibility of C(sp)-N reductive elimination in Au(III)-azide complexes, the gold-catalyzed C(sp)-N cross-coupling reaction has been achieved. Furthermore, it is shown that the Au(III)-azide complexes undergo facile azide exchange with cyano and alkyne nucleophiles, facilitating C(sp)-C(sp) cross-coupling.
在此，我们报告了新型（P^N）芳基金（III）-叠氮配合物的合成与表征。还证明了这些金（III）配合物通过还原消除形成C（sp）-N键。考虑到金（III）-叠氮配合物中C（sp）-N还原消除的可行性，实现了金催化的C（sp）-N交叉偶联反应。此外，结果表明金（III）-叠氮配合物能与氰基和炔基亲核试剂轻松进行叠氮交换，促进了C（sp）-C（sp）交叉偶联。
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