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基于CeO-FeO-氧化石墨烯的用于带有无线氢传感器的射频识别标签的高导电性石墨糊剂。

High conductivity graphite paste for radio frequency identification tag with wireless hydrogen sensor based on CeO-FeO-graphene oxide.

作者信息

Mojtabazadeh Hossein, Safaei-Ghomi Javad

机构信息

Department of Organic Chemistry, Faculty of Chemistry, University of Kashan P.O. Box 87317-51167 Kashan I. R. Iran

出版信息

RSC Adv. 2025 Apr 22;15(16):12773-12784. doi: 10.1039/d5ra00587f. eCollection 2025 Apr 16.

Abstract

Radio frequency identification (RFID) technology has made significant strides in recent years, opening up a world of possibilities for various industries. However, to achieve success, reliable and accurate real-time data is crucial. One exciting application of RFID technology is fast and wireless detection of gases. Hydrogen, in particular, is considered a clean fuel. However, it is highly flammable, and detecting it quickly and accurately is challenging in various industries. In this regard, our research focuses on developing a high-conductivity graphite paste for RFID tags integrated with a wireless hydrogen sensor based on nano-CeO-FeO-graphene oxide. In this work, we obtained a graphite paste using Ultra High Power (UHP) graphite electrodes with a high conductivity of 4.75 × 10 S cm for non-metallic substrates and 4 × 10 S cm with aluminum substrate. Furthermore, we incorporated a hydrogen gas detection sensor into the RFID tag utilizing graphene oxide and cerium oxide-iron oxide nanoparticles. The sensor demonstrated high sensitivity to low concentrations of H gas (1 ppm), with stable and repeatable performance. The wireless sensing response was evaluated through reflection coefficient ( ) measurements, confirming effective impedance matching between the RFID chip and antenna. Through this research, we aim to promote the advancement of RFID technology by introducing a low-cost, battery-free sensing platform using graphite and nano-engineered materials, suitable for diverse industrial applications.

摘要

近年来,射频识别(RFID)技术取得了重大进展,为各个行业开辟了一个充满可能性的世界。然而,要取得成功,可靠且准确的实时数据至关重要。RFID技术一个令人兴奋的应用是对气体进行快速无线检测。特别是氢气,被视为一种清洁燃料。然而,它高度易燃,在各个行业中快速准确地检测它具有挑战性。在这方面,我们的研究重点是开发一种用于RFID标签的高导电性石墨浆料,该浆料集成了基于纳米CeO-FeO-氧化石墨烯的无线氢气传感器。在这项工作中,我们使用超高功率(UHP)石墨电极获得了一种石墨浆料,对于非金属基板,其电导率为4.75×10 S cm,对于铝基板,电导率为4×10 S cm。此外,我们将氢气检测传感器集成到RFID标签中,利用氧化石墨烯和氧化铈-氧化铁纳米颗粒。该传感器对低浓度的H气体(1 ppm)表现出高灵敏度,具有稳定且可重复的性能。通过反射系数()测量评估无线传感响应,证实了RFID芯片与天线之间有效的阻抗匹配。通过这项研究,我们旨在通过引入一种使用石墨和纳米工程材料的低成本、无电池传感平台来推动RFID技术的进步,该平台适用于各种工业应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b044/12013617/1dd318fa71c8/d5ra00587f-f1.jpg

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