Anh Do Thao, Tran Nguyen Bao, La Ngoc Tran Nguyen, Huy Tran Huu, Kim Chi Tran Thi, Huong Giang Tran Thi, Tran Van Man, Pham Nguyet N T, Nguyen Tuan Loi, Thi Tran Nhu Hoa
Center for Innovative Materials and Architectures (INOMAR) Ho Chi Minh City 700000 Vietnam.
Vietnam National University Ho Chi Minh City 700000 Vietnam
RSC Adv. 2025 Apr 22;15(16):12746-12756. doi: 10.1039/d5ra01206f. eCollection 2025 Apr 16.
Herein, α-FeO-ZnO/C (FZC) nanocomposite samples were synthesized a chemical co-precipitation method, followed by a one-step heat-treatment at different temperatures to serve as anode materials. The advantages of FZC include a high specific surface area, a porous structure that facilitates rapid ion/electron transport, and additional active sites for lithium ions, leading to excellent electrical conductivity and superior electrochemical performance. The FZC4 material demonstrated a high charge/discharge capacity of 561.2/587.8 mA h g after 80 cycles at a current density of 0.1 A g, with low impedance and a coulombic efficiency (CE) of 95.4%. The outstanding electrochemical performance of the FZC nanocomposites can be attributed to the synergistic effect between the hematite (α-FeO) nanoparticles and ZIF-8-derived platform framework, which significantly enhanced the lithium storage capacity of the anode. Our work provides an additional contribution to the field of nanomaterial research, expanding the potential for developing efficient and sustainable energy storage solutions in the future.
在此,采用化学共沉淀法合成了α-FeO-ZnO/C(FZC)纳米复合样品,随后在不同温度下进行一步热处理以用作阳极材料。FZC的优点包括高比表面积、有利于快速离子/电子传输的多孔结构以及锂离子的额外活性位点,从而导致优异的导电性和卓越的电化学性能。FZC4材料在0.1 A g的电流密度下循环80次后,表现出561.2/587.8 mA h g的高充/放电容量,具有低阻抗和95.4%的库仑效率(CE)。FZC纳米复合材料出色的电化学性能可归因于赤铁矿(α-FeO)纳米颗粒与ZIF-8衍生的平台框架之间的协同效应,这显著提高了阳极的锂存储容量。我们的工作为纳米材料研究领域做出了额外贡献,扩大了未来开发高效可持续储能解决方案的潜力。