Zhang Guo-Dong, Gao Yuan, Yu Pi-Hang, Zhang Chao, Guo Chuan-Hui, Ramakrishna Seeram, Long Yun-Ze, Zhang Jun
Shandong Key Laboratory of Medical and Health Textile Materials, Collaborative Innovation Center for Nanomaterials & Devices, College of Physics, Qingdao University, Qingdao 266071, China.
Center for Nanofibers & Nanotechnology, Department of Mechanical Engineering, National University of Singapore, Singapore 117574, Singapore.
Nanomaterials (Basel). 2025 Apr 11;15(8):578. doi: 10.3390/nano15080578.
Water is the most environmentally friendly solvent; however, conventional solution spinning using water as a solvent is challenging due to its low evaporation rate. We developed a double-pronged solution blow spinning (DP-SBS) system. This spinning technique significantly enhances solvent evaporation, and the designed structure (double-pronged) avoids the common problem of needle clogging caused by heating. DP-SBS enables high-yield production of water-soluble polymer nanofibers, with a production rate of up to 5.94 g/h, which far exceeds what can be achieved with traditional electrospinning or solution blow spinning. This method is also highly efficient for producing non-water-soluble polymer nanofibers, achieving a production rate of up to 7.91 g/h, the highest reported value to date. Additionally, this approach can be used to produce not only common two-dimensional fiber membranes but also fiber sponges in a single step using the double-pronged airflow system. For the first time, chitosan nanofiber sponges were successfully produced and demonstrated to have excellent hemostatic properties in medical hemostasis. This method can also be extended to the production of other 3D nanomaterials, such as mullite nanofiber sponges, which exhibit outstanding thermal insulation performance at high temperatures.
水是最环保的溶剂;然而,由于水的蒸发速率低,使用水作为溶剂进行传统的溶液纺丝具有挑战性。我们开发了一种双管齐下的溶液吹纺(DP-SBS)系统。这种纺丝技术显著提高了溶剂蒸发速率,并且所设计的结构(双管)避免了加热导致的针头堵塞这一常见问题。DP-SBS能够高产率地生产水溶性聚合物纳米纤维,生产率高达5.94克/小时,这远远超过了传统静电纺丝或溶液吹纺所能达到的产量。该方法对于生产非水溶性聚合物纳米纤维也非常高效,生产率高达7.91克/小时,这是迄今为止报道的最高值。此外,这种方法不仅可以用于生产常见的二维纤维膜,还可以使用双管气流系统一步生产纤维海绵。首次成功制备了壳聚糖纳米纤维海绵,并证明其在医疗止血方面具有优异的止血性能。该方法还可以扩展到生产其他3D纳米材料,如莫来石纳米纤维海绵,其在高温下表现出出色的隔热性能。