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研究用于电磁应用的3D打印碳-羰基铁复合材料。

Investigating 3D-Printed Carbon-Carbonyl Iron Composites for Electromagnetic Applications.

作者信息

Tsyhanok Dzmitry, Meisak Darya, Blyweert Pauline, Selskis Algirdas, Macutkevič Jan, Banys Jūras, Fierro Vanessa, Celzard Alain

机构信息

Physics Faculty, Vilnius University, Sauletekio av. 9, LT-10222 Vilnius, Lithuania.

CNRS-Centre National de la Recherche Scientifique, Université de Lorraine-IJL, F-88000 Épinal, France.

出版信息

Polymers (Basel). 2025 Apr 8;17(8):1009. doi: 10.3390/polym17081009.

Abstract

The electromagnetic properties of 3D-printed carbon-carbonyl iron powder (CIP) composites are studied in the radio (20 Hz-1 MHz) and microwave (26-37 GHz) frequency ranges. Relatively high electrical conductivities (about several hundred S/m), typical for these structures in the radio frequency range, are observed. The temperature dependence of electrical conductivity is described by Arrhenius' law, with distinct activation energies above and below a critical temperature, attributed to electron transport through various defects. The microwave properties of the investigated structures are particularly noteworthy. For instance, a 2 mm-plate with 20 wt.% magnetic inclusions achieves 52% absorption at 35 GHz. The microwave dielectric properties of the composite structures strongly depend on the concentration of carbonyl iron particles, with the highest values of the imaginary part of complex dielectric permittivity observed in carbon structures containing 20 wt.% CIP. Moreover, carbon composites with the highest CIP concentration exhibited interesting resonance states, demonstrating significant potential for Salisbury screen applications.

摘要

研究了3D打印碳-羰基铁粉(CIP)复合材料在射频(20 Hz - 1 MHz)和微波(26 - 37 GHz)频率范围内的电磁特性。在射频范围内观察到这些结构具有相对较高的电导率(约几百S/m)。电导率的温度依赖性由阿伦尼乌斯定律描述,在临界温度上下具有不同的活化能,这归因于电子通过各种缺陷的传输。所研究结构的微波特性尤其值得注意。例如,含有20 wt.%磁性夹杂物的2 mm厚板材在35 GHz时实现了52%的吸收率。复合结构的微波介电特性强烈依赖于羰基铁颗粒的浓度,在含有20 wt.% CIP的碳结构中观察到复介电常数虚部的最高值。此外,具有最高CIP浓度的碳复合材料表现出有趣的共振状态,显示出在萨利斯伯里屏应用方面的巨大潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/aacc/12030330/7a644995953c/polymers-17-01009-g001.jpg

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