Double-Walled Mesoporous Hydrogen-Bonded Organic Frameworks with High Methane Storage Capacity.

The development of mesoporous hydrogen-bonded organic frameworks (HOFs) is critically important for various applications, yet it poses significant challenges. Herein, we present the synthesis and characterization of a robust mesoporous HOF, RP-H200, constructed through the orchestration of π-π stacking and hydrogen bonding interactions in a 2-fold interpenetrated framework. RP-H200 features a unique double-walled structure with a pore size of 3.6 nm, representing the largest pore size among reported HOFs to date. The framework exhibits a high surface area of 2313 m g, with aromatic surfaces dominating the mesoporous channels. The methane storage performance of RP-H200 reaches a high capacity of 0.31 g g at 270 K/100 bar and 0.25 g g at 296 K/100 bar. The combination of large permanent mesoporosity, excellent thermal stability, and high surface area in RP-H200 makes it a promising candidate for clean energy storage and other functions.