A significant challenge in valorizing food waste is the accurate extraction and identification of metabolites, as the composition of phenolic compounds varies by plant species, part, growth conditions, and processing. This review examined phenolic compounds in plant residue groups (leaves/stalks, peels/husks, pulp/pomace, and seeds) to verify the predominance of specific compounds in the same plant groups, establishing a comprehensive database. This database may be helpful for future studies that seek sources of a given compound or develop solvents to extract phenolic compounds from a specific material. Moreover, the primary plant residues and trends in extracting and analyzing these compounds were reviewed. The predominance of specific compounds within these groups, such as luteolin in plant leaves and stalks, was observed. Most studies focus on extracts with the highest total phenolic content (TPC), limiting insights into how extraction variables affect the target compounds. Chromatographic methods vary according to sample type, column, and conditions, shifting toward reducing acetone/methanol use, shortening the analysis time, and integrating inline UV-vis detection. This perspective highlights plant residue parts rich in specific phenolics, contributing to more targeted, selective, and sustainable extraction methodologies.