Rahmani Hossein, Algirdas Augonis, Shestavetska Anhelina, Vaiciukyniene Danute
Faculty of Civil Engineering and Architecture, Kaunas University of Technology, Kaunas, Lithuania.
Sci Rep. 2025 Apr 29;15(1):14981. doi: 10.1038/s41598-025-98658-w.
This study investigates the development and performance of carbonized bio-composites derived from wood sawdust, integrated with sustainable binders such as cement, lime, and shale ash, to create environmentally friendly construction materials. The research systematically optimizes mix compositions and curing techniques to enhance mechanical properties, softening, and sustainability, with a focus on reducing cement content and mitigating CO emissions. Wood sawdust, treated with various solutions (water, Al(SO), CaCl, Ca(OH)), was combined with binders and additives (sand, shale ash) in precise proportions, followed by a controlled carbonization process (19% CO, 65% RH). Compressive strength tests revealed that cement-based composites with water-treated sawdust and 20% sand achieved a 44% strength increase (up to 9.6 MPa), while 30% cement replacement with shale ash yielded a 55% strength gain and improved water resistance (softening coefficient: 0.55). Carbonization, preceded by air-drying, further enhanced strength by 12% and density by 2%, demonstrating superior durability under moisture exposure. X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses confirmed the formation of calcite and a cohesive microstructure, respectively, underpinning the mechanical improvements. CO emissions were reduced by up to 65% in optimized formulations compared to traditional cement production, aligning with circular economy principles. These bio-composites, suitable for lightweight masonry applications, outperform prior sawdust-based materials (1-3 MPa) in strength and sustainability. This work advances the field of sustainable construction by offering a scalable, high-performance alternative to conventional materials, with rigorous methodology and robust data supporting its potential for industrial adoption.
本研究调查了源自木屑的碳化生物复合材料的开发与性能,该材料与水泥、石灰和页岩灰等可持续粘结剂相结合,以制造环保型建筑材料。该研究系统地优化了混合料组成和养护技术,以提高机械性能、软化性能和可持续性,重点是减少水泥用量和减少碳排放。用各种溶液(水、硫酸铝、氯化钙、氢氧化钙)处理过的木屑与粘结剂和添加剂(沙子、页岩灰)按精确比例混合,随后进行可控碳化过程(19%二氧化碳、65%相对湿度)。抗压强度试验表明,用水处理过的木屑和20%沙子制成的水泥基复合材料强度提高了44%(高达9.6兆帕),而用页岩灰替代30%的水泥则使强度提高了55%,并改善了耐水性(软化系数:0.55)。在空气干燥后进行碳化,强度进一步提高了12%,密度提高了2%,表明在潮湿环境下具有优异的耐久性。X射线衍射(XRD)和扫描电子显微镜(SEM)分析分别证实了方解石的形成和粘结微观结构的形成,这为机械性能的改善提供了支撑。与传统水泥生产相比,优化配方中的二氧化碳排放量减少了高达65%,符合循环经济原则。这些生物复合材料适用于轻质砌体应用,在强度和可持续性方面优于先前的木屑基材料(1-3兆帕)。这项工作通过提供一种可扩展的、高性能的传统材料替代品,推进了可持续建筑领域的发展,其严格的方法和可靠的数据支持了其在工业应用中的潜力。