Keppler Nils Christian, Steinbach Lukas, Fricke Johanna, Hannebauer Adrian, Rohloff Erik, Schaate Andreas, Behrens Peter
Institute of Inorganic Chemistry, Leibniz University Hannover, Hannover 30167, Germany.
Cluster of Excellence PhoenixD (Photonics, Optics and Engineering - Innovation Across Disciplines), Leibniz University Hannover, Hannover 30167, Germany.
ACS Appl Mater Interfaces. 2025 May 14;17(19):28830-28840. doi: 10.1021/acsami.5c02529. Epub 2025 May 1.
Due to their high chemical and thermal stability, zeolitic imidazolate frameworks (ZIFs) are interesting materials for various applications. To adapt ZIFs for new applications, such as optics, it is necessary to achieve precise shaping and control over film formation. Thin films are ideal for this purpose, as several of them are commonly used in optical devices. Here, we present a variety of different ZIF thin films that are accessible by applying a ZIF-8 seeding layer approach. High-quality ZIF-8 thin films are used as a seeding layer for the rapid production of other ZIF layers. All ZIFs are provided in high optical quality and have been characterized with respect to their optical properties. The presented thin films can also be fabricated as stacked layers with the desired order of different ZIFs to form photonic crystal structures, such as Bragg-stacks. Depending on the system, the fabrication of the stacked layers takes only a few hours. Finally, the thin films are loaded with guest molecules to influence their optical properties. Subsequent selective loading of the pores in ZIF 8/ZIF 90 stacks was achieved by using guest molecules of different polarity.
由于其高化学稳定性和热稳定性,沸石咪唑酯骨架材料(ZIFs)是适用于各种应用的有趣材料。为了使ZIFs适用于新的应用,如光学领域,实现精确成型和对成膜的控制是必要的。薄膜非常适合此目的,因为它们中的几种常用于光学器件。在此,我们展示了通过应用ZIF-8种子层方法可获得的多种不同的ZIF薄膜。高质量的ZIF-8薄膜用作快速制备其他ZIF层的种子层。所有ZIFs均具有高光学质量,并已对其光学性质进行了表征。所展示的薄膜还可以制成具有不同ZIF所需顺序的堆叠层,以形成光子晶体结构,如布拉格堆叠。根据系统的不同,堆叠层的制备仅需几个小时。最后,在薄膜中加载客体分子以影响其光学性质。通过使用不同极性的客体分子,实现了对ZIF 8/ZIF 90堆叠中孔的后续选择性加载。
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