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基于四苯基咪唑衍生物的有机合成及性质研究进展

Advances in Organic Synthesis and Properties Based On Tetraphenylimidazole Derivatives.

作者信息

Huang Huibin, Li Yang, Zeng Can, Chen Jiali, Liu Ming, Wu Hanqing

机构信息

School of Materials Science and Engineering, Guangdong University of Petrochemical Technology, Maoming, 525000, People's Republic of China.

Guangdong University of Petrochemical Technology, Maoming, 525000, People's Republic of China.

出版信息

J Fluoresc. 2025 May 2. doi: 10.1007/s10895-025-04328-5.

DOI:10.1007/s10895-025-04328-5
PMID:40314892
Abstract

1,2,4,5-Tetraphenylimidazole derivatives exhibit unique conjugated structures, photophysical properties, and multifunctional properties by virtue of the phenyl functional groups introduced at specific positions of the imidazole ring. However, there is still a lack of systematic research on them, which limits their further development and application. In this paper, we comprehensively review the research progress in the fields of organic synthesis, mechanistic fluorescence color change, chemiluminescence, OLED and fluorescent sensors, especially focusing on the hotspot of fluorescent sensors. Finally, it summarizes the challenges in the current research and looks forward to the future research directions, such as the design of novel structures, performance optimization, and exploration of practical applications, aiming to provide references and inspirations for researchers in related fields.

摘要

1,2,4,5-四苯基咪唑衍生物由于在咪唑环的特定位置引入了苯基官能团,展现出独特的共轭结构、光物理性质和多功能性质。然而,目前对它们仍缺乏系统的研究,这限制了它们的进一步发展和应用。本文全面综述了其在有机合成、机械荧光变色、化学发光、有机发光二极管和荧光传感器等领域的研究进展,尤其聚焦于荧光传感器这一热点。最后,总结了当前研究中的挑战,并展望了未来的研究方向,如新型结构设计、性能优化以及实际应用探索等,旨在为相关领域的研究人员提供参考和启示。

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Various synthesis and biological evaluation of some tri -tetra-substituted imidazoles derivatives: A review.一些三 - 四取代咪唑衍生物的各种合成方法及生物学评价:综述
Heliyon. 2024 May 16;10(10):e31253. doi: 10.1016/j.heliyon.2024.e31253. eCollection 2024 May 30.
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D-π-A-π-D-Configured Imidazole-Tethered Benzothiadiazole-Based Sensor for the Ratiometric Discrimination of Picric Acid: Applications in Latent Fingerprint Imaging.
用于苦味酸比例识别的 D-π-A-π-D 构型咪唑连接苯并噻二唑基传感器:在潜在指纹成像中的应用
J Org Chem. 2024 Apr 19;89(8):5392-5400. doi: 10.1021/acs.joc.3c02803. Epub 2024 Apr 2.
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Multicomponent Synthesis of Fluorescent Thiazole-Indole Hybrids and Thiazole-Based Novel Polymers.噻唑-吲哚杂化荧光化合物及噻唑基新型聚合物的多组分合成。
J Org Chem. 2022 Sep 2;87(17):11399-11413. doi: 10.1021/acs.joc.2c00922. Epub 2022 Aug 23.
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Deep insight into reasons for the mechanoluminescence phenomenon of triphenylamine-substituted imidazoles and their distinct mechano-fluorochromic behaviours.深入探究三苯胺取代咪唑的机械发光现象及其独特的机械荧光变色行为的原因。
RSC Adv. 2020 Jun 17;10(39):23187-23195. doi: 10.1039/d0ra02737e. eCollection 2020 Jun 16.
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Hydroxy-Tetraphenylimidazole Derivatives as Efficient Blue Emissive Materials for Electroluminescent Devices.羟基四苯基咪唑衍生物作为电致发光器件的高效蓝色发光材料
Chem Asian J. 2022 Jul 15;17(14):e202200266. doi: 10.1002/asia.202200266. Epub 2022 May 24.
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RSC Adv. 2022 Feb 2;12(7):4358-4369. doi: 10.1039/d1ra07984k. eCollection 2022 Jan 28.
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