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基于正电子发射断层扫描(PET)的杂原子掺杂碳量子点作为颜色调制的固态荧光材料。

PET-derived heteroatom-doped carbon quantum dots as color-modulated solid-state fluorescent materials.

作者信息

Promcharoen Peerapong, Chumkaeo Peerapong, Charoenchaidet Sunichaya, Charoenchaidet Sumate, Somsook Ekasith

机构信息

NANOCAST Laboratory, Center for Catalysis Science and Technology (CAST), Department of Chemistry, Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University 272 Rama VI Rd., Ratchathewi Bangkok 10400 Thailand

Triam Udom Suksa School 227 Phaya Thai Rd., Pathum Wan Bangkok 10330 Thailand.

出版信息

RSC Adv. 2025 May 6;15(18):14420-14427. doi: 10.1039/d5ra02014j. eCollection 2025 Apr 28.

Abstract

Plastic waste was transformed into high-performance quantum dots (QDs), combining technological innovation with a focus on environmental sustainability. The excellent fluorescence properties of the synthesized quantum dots were utilized to detect Fe and F ions with high sensitivity and selectivity in an "on-off-on" dual-mode fashion. Additionally, the synthesized quantum dots exhibited stable solid-state fluorescence, enabling their use in solid-phase applications without the typical fluorescence loss observed in other materials. The versatility and tunability of the synthesized materials were demonstrated by producing three different emission colors, achieved through the incorporation of various heteroatoms during the synthesis process. This solid-state fluorescent material provides a pathway for sensing and optoelectronic applications, as well as advanced optical devices with customizable designs in the future.

摘要

塑料垃圾被转化为高性能量子点(QDs),将技术创新与对环境可持续性的关注结合在一起。合成的量子点具有优异的荧光特性,可用于以“开-关-开”双模式高灵敏度和高选择性地检测铁离子和氟离子。此外,合成的量子点表现出稳定的固态荧光,使其能够用于固相应用,而不会出现其他材料中常见的荧光损失。通过在合成过程中引入各种杂原子,制备出三种不同发射颜色的材料,证明了合成材料的多功能性和可调性。这种固态荧光材料为传感和光电子应用以及未来具有可定制设计的先进光学器件提供了一条途径。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ee81/12053552/2d529aa4dbae/d5ra02014j-f1.jpg

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