Zhang Haiyang, Li Zeyu, Xiao Daihong, Wu Mingdong, Huang Yang, Liu Wensheng
National Key Laboratory of Science and Technology on High-Strength Structural Materials, Central South University, Changsha 410083, China.
Materials (Basel). 2025 Apr 9;18(8):1706. doi: 10.3390/ma18081706.
The existing Al-Ce heat-resistant alloys are not extensively utilized in high-temperature applications due to their poor room-temperature mechanical properties. In this study, the Al-10Ce-3Mg-5Zn alloy was enhanced using hot extrusion and heat treatment. The as-extruded alloy exhibited bimodal intermetallic compounds and grain structures. Additionally, high-density microcracks and twins were observed in the micron-sized intermetallic compounds. Compared with the as-cast state, the as-extruded alloy demonstrated a higher ultimate tensile strength (UTS) of 317 MPa and better elongation of 11.0%. Numerous nano-sized T phases precipitated in the α-Al matrix after the heat treatment, contributing to a further rise in UTS (365 MPa). The high strength of the alloy is primarily due to its strong strain hardening capacity, fine grain strengthening, and precipitation strengthening effect. The change in elongation mainly results from the expansion of pre-existing microcracks, twin deformation, and microstructural refinement. The heat-treated alloys exhibited superior strength retention ratios at elevated temperatures (64% at 200 °C) compared to conventional heat-resistant aluminum alloys. The results of this paper indicate that hot extrusion and heat treatment are effective for developing heat-resistant Al-Ce alloys with high room-temperature strength, offering a simple process suitable for industrial production.
现有的铝铈耐热合金由于其室温力学性能较差,在高温应用中未得到广泛应用。在本研究中,通过热挤压和热处理对Al-10Ce-3Mg-5Zn合金进行了强化。挤压态合金呈现出双峰金属间化合物和晶粒结构。此外,在微米级金属间化合物中观察到高密度微裂纹和孪晶。与铸态相比,挤压态合金的极限抗拉强度(UTS)更高,为317 MPa,伸长率更好,为11.0%。热处理后,α-Al基体中析出大量纳米级T相,使UTS进一步提高(365 MPa)。合金的高强度主要归因于其强大的应变硬化能力、细晶强化和析出强化效果。伸长率的变化主要源于预先存在的微裂纹扩展、孪晶变形和微观结构细化。与传统耐热铝合金相比,热处理后的合金在高温下表现出优异的强度保持率(200℃时为64%)。本文结果表明,热挤压和热处理对于开发具有高室温强度的耐热铝铈合金是有效的,提供了一种适用于工业生产的简单工艺。