Zhang Haiyang, Wu Mingdong, Li Zeyu, Xiao Daihong, Huang Yang, Huang Lanping, Liu Wensheng
National Key Laboratory of Science and Technology on High-Strength Structural Materials, Central South University, Changsha 410083, China.
Materials (Basel). 2024 Aug 12;17(16):3999. doi: 10.3390/ma17163999.
The microstructure and mechanical properties of as-cast Al-10Ce-3Mg-xZn (x = 0, 1, 3, 5 wt.%) alloys were systematically investigated, with a focus on the effect of Zn on the AlCe reinforcing phase in the alloy. The results showed that the Al-10Ce-3Mg alloy consists of α-Al, a Chinese-script AlCe eutectic phase, and a massive AlCe primary phase. With the addition of Zn content, most of the Zn atoms are enriched in the AlCe phase to form the acicular-like AlCeZn phase within the AlCe phase. Increasing the Zn content can increase the volume fraction of the AlCe phase. Compared to the alloy without Zn addition, the microhardness and elastic modulus of the AlCeZn-reinforced AlCe phase in the alloy with 5 wt.% Zn increased by 18.9% and 9.0%, respectively. Moreover, the room-temperature mechanical properties of Al-10Ce-3Mg alloys were significantly improved due to the addition of Zn element. The alloy containing 5 wt.% Zn had the best tensile properties with an ultimate tensile strength of 210 MPa and a yield strength of 171MPa, which were 21% and 77% higher than those of the alloy without Zn, respectively. The alloy containing 5 wt.% Zn demonstrated a superior retention ratio of tensile strength at 200-300 °C, indicating that the alloy has excellent heat resistance. The improvement in the mechanical properties is primarily attributed to second-phase strengthening and solid solution strengthening.
系统研究了铸态Al-10Ce-3Mg-xZn(x = 0、1、3、5 wt.%)合金的微观结构和力学性能,重点关注Zn对合金中AlCe增强相的影响。结果表明,Al-10Ce-3Mg合金由α-Al、汉字状AlCe共晶相和块状AlCe初生相组成。随着Zn含量的增加,大部分Zn原子富集在AlCe相中,在AlCe相内形成针状AlCeZn相。增加Zn含量可提高AlCe相的体积分数。与未添加Zn的合金相比,含5 wt.% Zn合金中AlCeZn增强的AlCe相的显微硬度和弹性模量分别提高了18.9%和9.0%。此外,由于添加了Zn元素,Al-10Ce-3Mg合金的室温力学性能得到显著改善。含5 wt.% Zn的合金具有最佳的拉伸性能,其极限抗拉强度为210 MPa,屈服强度为171MPa,分别比未添加Zn的合金高21%和77%。含5 wt.% Zn的合金在200-300 °C时表现出优异的抗拉强度保持率,表明该合金具有出色的耐热性。力学性能的改善主要归因于第二相强化和固溶强化。