Yao Wenhao, Wu Wenying, Liu Yitong, Zhu Bingfa, Xiao Jifa, Zhang Teng, Xi Senliang
Key Laboratory of Cluster Science Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Advanced Research Institute of Multidisciplinary Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China.
Advanced Technology Research Institute (Jinan), Beijing Institute of Technology, Jinan 250000, China.
Molecules. 2025 Apr 13;30(8):1737. doi: 10.3390/molecules30081737.
Ammonia is one of the most widely produced inorganic chemicals, with extensive applications in the military, agricultural, and industrial sectors. However, its strong stimulation and corrosive properties pose significant health risks, as long-term exposure to ammonia environments can lead to respiratory tract damage, loss of consciousness, and even cardiopulmonary dysfunction. Over the years, researchers have focused on exploring suitable materials for ammonia adsorption fields such as activated carbon and zeolites. Porous framework materials (PFMs), including metal-organic frameworks, covalent organic frameworks, and hydrogen-bonded organic frameworks, have emerged as possible ammonia adsorption materials due to their high specific surface area, pore size, and structural adjustability. This review focuses on the research and application of materials with excellent adsorption based on PFMs for ammonia adsorption, highlighting their potential applications and providing insights into future developments in this field.
氨是产量最高的无机化学品之一，在军事、农业和工业领域有着广泛应用。然而，其强烈的刺激性和腐蚀性会带来重大健康风险，因为长期暴露在氨气环境中会导致呼吸道损伤、意识丧失，甚至心肺功能障碍。多年来，研究人员一直致力于探索适用于氨吸附领域的材料，如活性炭和沸石。多孔框架材料（PFMs），包括金属有机框架、共价有机框架和氢键有机框架，因其高比表面积、孔径和结构可调节性，已成为可能的氨吸附材料。本文综述聚焦于基于多孔框架材料的具有优异吸附性能的材料在氨吸附方面的研究与应用，突出其潜在应用，并对该领域的未来发展提供见解。
