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碳纳米管和固化剂浓度对聚二甲基硅氧烷力学、热学和电学性能的影响:优化与统计分析

Effects of carbon nanotube and curing agent concentrations on the mechanical, thermal and electrical properties of polydimethylsiloxane: optimization and statistical analysis.

作者信息

Laftah Waham Ashaier, Wan Abdul Rahman Wan Aizan, Ibrahim Akos Noel

机构信息

Department of Polymers and Petrochemical Engineering, College of Oil and Gas Engineering, Basra University for Oil and Gas Basra 61004 Iraq

Department of Bioprocess and Polymer Engineering, School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia 81310 UTM Skudai Johor Malaysia.

出版信息

RSC Adv. 2025 May 7;15(19):14838-14847. doi: 10.1039/d5ra01890k. eCollection 2025 May 6.

Abstract

This study examined the combined impact of carbon nanotubes (CNTs) and curing agents on the mechanical properties (tensile strength and modulus of elasticity) and thermal and electrical conductivities of polydimethylsiloxane (PDMS) using statistical analysis. PDMS composites were created by varying the concentrations of CNTs (0% to 5%) and curing agents (0% to 0.5%), and their properties such as tensile strength, modulus of elasticity, and thermal and electrical conductivities were comprehensively analyzed. Mechanical tests revealed that adding 5% CNT and 0.5% curing agent increased the tensile strength by 50% and modulus of elasticity (Young's modulus) by 65%, indicating a substantial reinforcing effect. Thermal conductivity remarkably improved from 0.2 W m K in pure PDMS to 1.1 W m K in the composite containing 5% CNT and 0.5% curing agent. The electrical conductivity improved significantly from an insulating 10 S m to 10 S m. This indicated a shift to conductive PDMS at higher CNT concentrations. Statistical analysis showed that CNTs had more significant impact on electrical and thermal properties, while the curing agent mainly enhanced the mechanical stability. These results highlight the combined potential of CNTs and curing agents in modifying PDMS properties for advanced engineering applications.

摘要

本研究运用统计分析方法,考察了碳纳米管(CNTs)和固化剂对聚二甲基硅氧烷(PDMS)力学性能(拉伸强度和弹性模量)以及热导率和电导率的综合影响。通过改变碳纳米管(0%至5%)和固化剂(0%至0.5%)的浓度制备了PDMS复合材料,并对其拉伸强度、弹性模量以及热导率和电导率等性能进行了全面分析。力学测试表明,添加5%的碳纳米管和0.5%的固化剂可使拉伸强度提高50%,弹性模量(杨氏模量)提高65%,显示出显著的增强效果。热导率从纯PDMS的0.2 W m K显著提高到含有5%碳纳米管和0.5%固化剂的复合材料中的1.1 W m K。电导率从绝缘的10 S m显著提高到10 S m。这表明在较高碳纳米管浓度下,PDMS转变为导电材料。统计分析表明,碳纳米管对电学和热学性能的影响更为显著,而固化剂主要增强了机械稳定性。这些结果突出了碳纳米管和固化剂在改性PDMS性能以用于先进工程应用方面的综合潜力。

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