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作为抗氧化活性指标的秘鲁香脂精油中蒎烯与五种主要成分的比例。

The pinene-to-five principal components ratio in Schinus molle L. essential oil as an antioxidant activity indicator.

作者信息

Mariani Elisa, Enemark Gisella Kay Guerberoff, Juncos Nicolle Stefani, Cravero Carolina Florencia, Olmedo Rubén Horacio

机构信息

CONICET, Centro Cientifico Tecnologico Córdoba, Córdoba, Argentina.

Universidad Nacional de Córdoba, Facultad de Ciencias Agropecuarias, Laboratorio de Tecnología de Alimentos (LabTA), Córdoba, Argentina.

出版信息

Food Chem. 2025 Sep 15;486:144653. doi: 10.1016/j.foodchem.2025.144653. Epub 2025 May 6.

Abstract

The objective of this study is to establish an indicator based on pinene content (α and β) for identifying Schinus molle and relate it to its antioxidant activity. Composition of Schinus molle essential oil (SEO) was analysed using gas chromatography and its thermal stability over a 14-day period at 60 °C. Antioxidant activity was evaluated with indirect measurement via Free Radical Scavenging Activity (FRSA-DDPH) and Total Phenolic Content and direct analysis by monitoring accelerated oxidation in sunflower oil over 14 days at 60 °C. Chemical, volatile, and sensory indicators of oxidation was measured. BHT was included as control antioxidant and SEO at 0.02 %, 0.10 % and 0.20 % w/w. SEO has no dose/response correlation between 0.10 and 0.20 % w/w. SEO demonstrated antioxidant properties, with the "pinene content to five main compounds" ratio, yielding a value of 0.39. Notably, ratios exceeding 0.10 were associated with the highest antioxidant activity, indicating potential industrial applications.

摘要

本研究的目的是建立一种基于蒎烯含量(α和β)的指标来鉴别秘鲁胡椒,并将其与抗氧化活性相关联。采用气相色谱法分析了秘鲁胡椒精油(SEO)的成分,并在60℃下考察了其14天的热稳定性。通过自由基清除活性(FRSA-DDPH)和总酚含量间接测定抗氧化活性,并通过监测60℃下向日葵油14天的加速氧化进行直接分析。测定了氧化的化学、挥发性和感官指标。将丁基羟基甲苯(BHT)作为对照抗氧化剂,并加入0.02%、0.10%和0.20%(w/w)的SEO。在0.10%至0.20%(w/w)之间,SEO没有剂量/反应相关性。SEO表现出抗氧化性能,“蒎烯含量与五种主要化合物的比例”值为0.39。值得注意的是,超过0.10的比例与最高的抗氧化活性相关,表明其具有潜在的工业应用价值。

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