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基于CaO-FeO-Fe-Pb并从废旧汽车电池阳极板回收的玻璃材料电化学性能增强

Enhancing Electrochemical Properties of Vitreous Materials Based on CaO-FeO-Fe-Pb and Recycled from Anodic Plate of a Spent Car Battery.

作者信息

Piscoiu Delia Niculina, Rada Simona, Vermesan Horatiu

机构信息

Faculty of Materials and Environmental Engineering, Technical University of Cluj-Napoca, 400641 Cluj-Napoca, Romania.

National Institute for Research and Development of Isotopic and Molecular Technologies, 400293 Cluj-Napoca, Romania.

出版信息

Materials (Basel). 2025 Apr 29;18(9):2017. doi: 10.3390/ma18092017.

DOI:10.3390/ma18092017
PMID:40363519
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12072264/
Abstract

This paper presents a novel approach for the recycling of spent anodic plates from lead-acid batteries through the melt quenching method using iron and calcium oxides and iron powder. The resulting recycled samples, with a 3CaO·5FeO·xFe·(92 - x)Pb composition, where x = 0, 1, 3, 5, 8, 10, 15, and 25% mol Fe, were characterized and analyzed in terms of their electrochemical performance. X-ray diffractograms show vitroceramic structures with varied crystalline phases. Analysis of the IR (infrared spectra) data shows a decrease of sulphate units due to doping with iron content. The ultraviolet-visible (UV-Vis) and electron spin resonance (ESR) data reveal the presence of Fe ions with varied coordination geometries. Cyclic and linear sweep voltammograms demonstrate that the samples with 8 and 10% Fe exhibit superior electrochemical performance compared to other vitroceramics. The electrochemical impedance spectroscopy measurements indicate that the sample with 8% Fe had lower resistance compared to other analogues and had enhanced electrical conductivity.

摘要

本文提出了一种新颖的方法，通过使用铁和钙的氧化物以及铁粉的熔体淬火法来回收铅酸电池用过的阳极板。所得的回收样品具有3CaO·5FeO·xFe·(92 - x)Pb的组成，其中x = 0、1、3、5、8、10、15和25%摩尔的铁，并对其电化学性能进行了表征和分析。X射线衍射图显示出具有不同晶相的微晶玻璃结构。对红外光谱数据的分析表明，由于铁含量的掺杂，硫酸盐单元减少。紫外可见（UV-Vis）和电子自旋共振（ESR）数据揭示了具有不同配位几何结构的铁离子的存在。循环伏安图和线性扫描伏安图表明，与其他微晶玻璃相比，含8%和10%铁的样品表现出优异的电化学性能。电化学阻抗谱测量表明，含8%铁的样品与其他类似物相比电阻较低，并且具有增强的电导率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/250650d4ce85/materials-18-02017-g013.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/7e86cb07367d/materials-18-02017-g007a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/77ee0948478e/materials-18-02017-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/355cb00d6c3b/materials-18-02017-g009a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/86443f3a3b13/materials-18-02017-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/635b3f63f966/materials-18-02017-g011a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/539d0ac110e2/materials-18-02017-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/250650d4ce85/materials-18-02017-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/3db350d7538d/materials-18-02017-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/348c19556a8e/materials-18-02017-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/10123ad45c96/materials-18-02017-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/a3bbb8f682ea/materials-18-02017-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/85cc87445608/materials-18-02017-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/720447e4ff77/materials-18-02017-g006a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/7e86cb07367d/materials-18-02017-g007a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/77ee0948478e/materials-18-02017-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/355cb00d6c3b/materials-18-02017-g009a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/86443f3a3b13/materials-18-02017-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/635b3f63f966/materials-18-02017-g011a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/539d0ac110e2/materials-18-02017-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a13a/12072264/250650d4ce85/materials-18-02017-g013.jpg

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