Mahawong Sirinad, Thaveemas Piyatida, Onsri Parichart, Kaowphong Sulawan, Watcharin Waralee, Techasakul Supanna, Dechtrirat Decha, Chuenchom Laemthong
Division of Physical Science, Faculty of Science, Prince of Songkla University, Songkhla 90112, Thailand.
Laboratory of Organic Synthesis, Chulabhorn Research Institute, Bangkok 10210, Thailand.
Molecules. 2025 May 3;30(9):2040. doi: 10.3390/molecules30092040.
The sugar industry produces significant quantities of waste biomass, while other industrial sectors generate iron scrap as waste. This study seeks to make use of these waste products using an in situ approach that integrates carbonization, activation, and magnetization to convert sugarcane waste and iron scrap into a magnetic carbon composite adsorbent. The porosity of the activated carbon was enhanced by the activating agent potassium hydroxide (KOH) and further improved by the addition of iron scrap, which also imparted magnetic properties to the composite. The developed porosity of the composite increased the overall adsorption capacity of the adsorbent. The synthesis conditions were varied to examine the effects on the properties of the adsorbent. The amount of KOH used in the synthesis influenced the performance of the material. The best-performing adsorbent demonstrated strong potential in the treatment of wastewater by exhibiting an adsorption capacity of 1736.93 mg/g for the antibiotic tetracycline. The magnetic properties of the composite adsorbent enable simple separation and recovery, making the adsorbent reusable and lowering operating costs. This study provides a clear framework for the synthesis of waste-derived magnetic carbon composite adsorbents that can offer financial and environmental advantages while remaining effective in industrial contexts.
制糖工业产生大量废弃生物质,而其他工业部门则产生废铁屑。本研究旨在采用一种原位方法利用这些废品,该方法整合了碳化、活化和磁化过程,将甘蔗废料和废铁转化为磁性碳复合吸附剂。活性炭的孔隙率通过活化剂氢氧化钾(KOH)得以提高,而废铁的添加进一步改善了孔隙率,同时赋予复合材料磁性。复合材料发达的孔隙率提高了吸附剂的整体吸附能力。通过改变合成条件来考察其对吸附剂性能的影响。合成过程中KOH的用量影响材料的性能。性能最佳的吸附剂对抗生素四环素的吸附容量为1736.93 mg/g,在废水处理中显示出强大的潜力。复合吸附剂的磁性使其能够简单地分离和回收,从而使吸附剂可重复使用并降低运营成本。本研究为合成源自废品的磁性碳复合吸附剂提供了清晰的框架,这种吸附剂在工业环境中既能带来经济和环境效益,又能保持有效性。