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用于电池和超级电容器的先进CdSe量子点：电化学前沿

Advancing CdSe quantum dots for batteries and supercapacitors: electrochemical frontiers.

作者信息

Kazemi Mosstafa, Noorizadeh Hadi, Jadeja Yashwantsinh, Saraswat Shelesh Krishna, M M Rekha, Shankhyan Aman, S Supriya, Joshi Kamal Kant

机构信息

Young Researchers and Elite Club, Tehran Branch, Islamic Azad University Tehran Iran

Marwadi University Research Center, Department of Chemistry, Faculty of Science, Marwadi University Rajkot-360003 Gujarat India.

出版信息

RSC Adv. 2025 May 14;15(20):16134-16163. doi: 10.1039/d5ra02414e. eCollection 2025 May 12.

DOI:10.1039/d5ra02414e
PMID:40370847
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12077318/
Abstract

Cadmium selenide (CdSe) quantum dots (QDs) have emerged as transformative nanomaterials in energy storage, leveraging their size-tunable electronic properties and high surface area to push the boundaries of batteries and supercapacitors. This review marks the first dedicated investigation of CdSe QDs specifically tailored for batteries and supercapacitors unraveling their potential to enhance charge storage, cycling stability, and electrochemical efficiency. We highlight cutting-edge advancements in integrating CdSe QDs into lithium-ion batteries, lithium-oxygen batteries, and supercapacitors, driven by innovative synthesis strategies and hybrid nanostructures. Key mechanisms, including pseudocapacitance and ion diffusion, are dissected to reveal how CdSe QDs elevate device performance. Despite cadmium toxicity challenges, breakthroughs in core-shell designs and surface passivation offer pathways to safer, high-performance systems. This work underscores CdSe QDs as pivotal players in next-generation electrochemical energy storage, bridging synthesis innovation with practical application.

摘要

硒化镉（CdSe）量子点（QDs）已成为储能领域具有变革性的纳米材料，利用其尺寸可调的电子特性和高比表面积来拓展电池和超级电容器的性能边界。本综述首次专门研究了为电池和超级电容器量身定制的CdSe量子点，揭示了它们在增强电荷存储、循环稳定性和电化学效率方面的潜力。我们强调了在创新合成策略和混合纳米结构的推动下，将CdSe量子点集成到锂离子电池、锂氧电池和超级电容器方面的前沿进展。剖析了包括赝电容和离子扩散在内的关键机制，以揭示CdSe量子点如何提升器件性能。尽管存在镉毒性挑战，但核壳设计和表面钝化方面的突破为更安全、高性能的系统提供了途径。这项工作强调了CdSe量子点在下一代电化学储能中的关键作用，将合成创新与实际应用联系起来。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c49/12077318/86e46239cda4/d5ra02414e-p1.jpg
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