Niranjana Vadakkaveedu Subramanian, Ponnan Sathiyanathan, Mukundan Arvind, Prabu Arun Anand, Wang Hsiang-Chen
Department of Chemistry, School of Advanced Sciences, Vellore Institute of Technology, Vellore 632014, India.
Department of Materials Science, Chulalongkorn University, Bangkok 10330, Thailand.
Polymers (Basel). 2025 May 21;17(10):1416. doi: 10.3390/polym17101416.
Nanomaterials (NMs) have gained tremendous attention in various applications in the modern era. The most significant challenge associated with NMs is their strong propensity to aggregate. The chemical surface modification of NMs has garnered notable attention in managing NM dispersion and aggregation. Among the modification approaches, the silane modification of NMs has generated great interest among researchers as a versatile approach to tailoring the surface characteristics of NMs. This review comprehensively examined the recent advancements in silane modification techniques with a focus on triboelectric nanogenerator (TENG) applications. It provides an overview of silane chemistry and its interaction with diverse NMs, elucidating the underlying mechanisms governing the successful surface functionalization process. This review emphasized the silane modification, such as improved mechanical properties of composites, enhanced electrical and thermal conductivity, functional coatings, water treatment, textile industries, catalysis, membrane applications, and biomedical applications, of various NMs. In particular, the role of silane-modified NMs in advancing energy harvesting technologies was highlighted, showcasing their potential to enhance the performance and stability of next-generation devices.
在现代,纳米材料在各种应用中受到了极大关注。与纳米材料相关的最重大挑战是它们极易聚集。纳米材料的化学表面改性在控制纳米材料的分散和聚集方面已引起显著关注。在各种改性方法中,纳米材料的硅烷改性作为一种定制纳米材料表面特性的通用方法,在研究人员中引起了极大兴趣。本综述全面研究了硅烷改性技术的最新进展,重点关注摩擦纳米发电机(TENG)应用。它概述了硅烷化学及其与各种纳米材料的相互作用,阐明了成功进行表面功能化过程的潜在机制。本综述强调了硅烷改性在各种纳米材料中的应用,如改善复合材料的机械性能、提高电导率和热导率、功能性涂层、水处理、纺织工业、催化、膜应用以及生物医学应用。特别是,突出了硅烷改性纳米材料在推进能量收集技术方面的作用,展示了它们增强下一代器件性能和稳定性的潜力。