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识别沿海气溶胶中的废水化学物质。

Identifying wastewater chemicals in coastal aerosols.

作者信息

Cooper Adam, Cancelada Lucia, Torres Ralph Riley, Belcher Kathryn, Small Mallory, Belda-Ferre Pedro, Morris Clare, Mitts Brock, Dinasquet Julie, Knight Rob, Slade Jonathan H, Prather Kimberly A

机构信息

Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093, USA.

Scripps Institution of Oceanography, University of California, San Diego, La Jolla, CA 92093, USA.

出版信息

Sci Adv. 2025 May 30;11(22):eads9476. doi: 10.1126/sciadv.ads9476. Epub 2025 May 28.

Abstract

The Tijuana River, at the US-Mexico border, discharges millions of gallons of wastewater daily-sewage, industrial waste, and runoff-into the Pacific Ocean, making it the dominant source of coastal pollution in this region. This study examines how such wastewater influences coastal aerosols by tracking spatial gradients from near the border northward. Using benzoylecgonine (a nonvolatile cocaine metabolite) as a sewage tracer, we find that wastewater compounds-including a mixture of illicit drugs, drug metabolites, and chemicals from tires and personal care products-become aerosolized and are detectable in both water and air. Spatial analyses confirm that most measured chemicals concentrate in aerosols near the Tijuana River, potentially exposing local populations to tens of nanograms per hour (e.g., octinoxate and methamphetamine) via inhalation. This airborne pathway highlights a largely overlooked source of atmospheric pollution, emphasizing the need to reassess health risks in coastal regions as global water contamination continues to escalate.

摘要

位于美墨边境的蒂华纳河每天向太平洋排放数百万加仑的废水(包括污水、工业废料和径流),使其成为该地区沿海污染的主要来源。本研究通过追踪从边境向北的空间梯度,考察此类废水如何影响沿海气溶胶。使用苯甲酰爱康宁(一种非挥发性可卡因代谢物)作为污水示踪剂,我们发现废水中的化合物(包括违禁药物、药物代谢物以及来自轮胎和个人护理产品的化学物质的混合物)会雾化,并在水和空气中均可检测到。空间分析证实,大多数测得的化学物质集中在蒂华纳河附近的气溶胶中,可能使当地居民通过吸入每小时接触到数十纳克(例如桂皮酸盐和甲基苯丙胺)。这种空气传播途径凸显了一个很大程度上被忽视的大气污染源,强调随着全球水污染持续加剧,有必要重新评估沿海地区的健康风险。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1cbc/12118540/30ecfee4527f/sciadv.ads9476-f1.jpg

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