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氢转移在功能性分子材料与器件中的作用。

Role of Hydrogen Transfer in Functional Molecular Materials and Devices.

作者信息

Zhang Enyu, Bai Liping, Chen Zhiping, Zhang Aobo, Tang Yingbo, Ran Jushang, Wang Shuai, Wang Jinying, Jia Chuancheng, Guo Xuefeng

机构信息

Center of Single-Molecule Sciences, Institute of Modern Optics, Frontiers Science Center for New Organic Matter, Tianjin Key Laboratory of Micro-Scale Optical Information Science and Technology, College of Electronic Information and Optical Engineering, Nankai University, 38 Tongyan Road, Jinnan District, Tianjin 300350, PR China.

Beijing National Laboratory for Molecular Sciences, National Biomedical Imaging Center, College of Chemistry and Molecular Engineering, Peking University, 202 Chengfu Road, Haidian District, Beijing 100871, PR China.

出版信息

Precis Chem. 2025 Mar 11;3(5):233-260. doi: 10.1021/prechem.4c00097. eCollection 2025 May 26.

Abstract

Hydrogen transfer is a fundamental chemical process critical to the design and application of organic molecules and functional devices. By uncovering the dynamic interactions between atoms within molecules, hydrogen transfer research offers innovative pathways for creating advanced functional materials and devices. These advancements have driven progress in areas such as optoelectronics, molecular switches, and bioimaging. This review explores the various forms of hydrogen transfer, including hydrogen atom, proton, and hydride transfer, highlighting their mechanisms and key reactions. It also examines the integration of these processes into molecular devices, including single-molecule systems, molecular films, and organic frameworks. Future directions emphasize precise control of hydrogen transfer pathways, development of highly selective and efficient reaction systems, and the design of robust devices based on these processes. These efforts aim to enhance device performance and broaden applications in intelligent materials, integrated functions, and information technology.

摘要

氢转移是一种基本的化学过程,对有机分子和功能器件的设计与应用至关重要。通过揭示分子内原子之间的动态相互作用,氢转移研究为创造先进功能材料和器件提供了创新途径。这些进展推动了光电子学、分子开关和生物成像等领域的进步。本综述探讨了氢转移的各种形式,包括氢原子、质子和氢化物转移,重点介绍了它们的机制和关键反应。它还研究了这些过程在分子器件中的整合,包括单分子系统、分子薄膜和有机框架。未来的方向强调对氢转移途径的精确控制、高选择性和高效反应系统的开发,以及基于这些过程的稳健器件的设计。这些努力旨在提高器件性能,并拓宽在智能材料、集成功能和信息技术中的应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f37f/12117429/8360aef86278/pc4c00097_0003.jpg

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