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基于蛋白质和多糖颗粒稳定的皮克林乳液凝胶:稳定性、合成、应用及展望综述

Pickering emulsion gels stabilized by protein and polysaccharide-based particles: A review of stability, synthesis, applications and prospective.

作者信息

Hashemi Behnaz, Assadpour Elham, Wang Yue, Jafari Seid Mahdi

机构信息

Institute of Leisure Agriculture, Shandong Academy of Agricultural Sciences, Jinan 250100, China.

Food Industry Research Co., Gorgan, Iran; Food and Bio-Nanotech International Research Center (Fabiano), Gorgan University of Agricultural Sciences and Natural Resources, Gorgan, Iran.

出版信息

Adv Colloid Interface Sci. 2025 Sep;343:103564. doi: 10.1016/j.cis.2025.103564. Epub 2025 May 30.

DOI:10.1016/j.cis.2025.103564
PMID:40451052
Abstract

With a far longer stability than traditional emulsions, Pickering emulsion gels (PKEGs)-stabilized by solid particles-have proven highly efficient in a range of applications during recent years. Particles based on proteins or polysaccharides with distinctive amphiphilic structure are particularly well-suited for the production of PKEGs because of their natural occurrence, low cost, high nutritional content, and potential health advantages. Thus far, it has been shown that plant and animal proteins, as well as their complexes with polysaccharides, effectively stabilize PKEGs. The three main mechanisms that protein-based particles (Pr-Particles) stabilize PKEGs are the formation of a densely packed interfacial layer due to the irreversible adsorption of Pr-Particles, the accumulation of non-adsorbed Pr-Particles at the plateau borders or the formation of a gel-like network in the continuous phase, which decreases drainage, and depletion stabilization. In some applications, each type of Pr-Particles may provide exceptional advantages. This paper summarizes the main functions of PKEGs stabilized by proteins or polysaccharides, looks at the key mechanisms governing gel stability to better understand the complex behavior of PKEGs, and highlights the important scientific, technological advancements being deployed in the food industry using PKEGs. Some important applications of PKEGs in the food and nutraceutical fields are delivery of bioactive compounds, modulation of lipid digestion, fat substitution and design/formulation of novel products including 3D printed foods, which have been covered in the current study.

摘要

皮克林乳液凝胶(PKEGs)由固体颗粒稳定,其稳定性远长于传统乳液,近年来已在一系列应用中证明具有高效性。基于具有独特两亲结构的蛋白质或多糖的颗粒,因其天然存在、低成本、高营养成分以及潜在的健康优势,特别适合用于生产PKEGs。到目前为止,已表明植物和动物蛋白以及它们与多糖的复合物能有效稳定PKEGs。基于蛋白质的颗粒(Pr - 颗粒)稳定PKEGs的三个主要机制是:由于Pr - 颗粒的不可逆吸附形成致密堆积的界面层;未吸附的Pr - 颗粒在平台边界处积累或在连续相中形成凝胶状网络,这会减少排液;以及耗尽稳定作用。在某些应用中,每种类型的Pr - 颗粒可能具有独特优势。本文总结了由蛋白质或多糖稳定的PKEGs的主要功能,研究了控制凝胶稳定性的关键机制,以便更好地理解PKEGs的复杂行为,并强调了在食品工业中使用PKEGs所取得的重要科学和技术进步。PKEGs在食品和营养保健品领域的一些重要应用包括生物活性化合物的递送、脂质消化的调节、脂肪替代以及新型产品(包括3D打印食品)的设计/配方,这些内容在本研究中均有涉及。

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