Bulky Cation-Modified Interfaces for Thermally Stable Lead Halide Perovskite Solar Cells.

Charged conjugated organic molecules offer promising prospects for reducing nonradiative recombination at interfaces in perovskite solar cells, while protecting the active layer from moisture. However, several studies have shown that the heat-induced diffusion of these cations leads to irreversible solar cell degradation. Passivation molecules for perovskite can reconstruct the film surface into lower-dimensional phases when exposed to thermal stress, impeding charge extraction and affecting the photoconversion efficiency (PCE) of devices. In this work, we study how molecular interactions between passivation molecules and 3D CsFAPbI perovskite impact stability and charge extraction at the perovskite/hole transport layer interfaces. Two model π-conjugated molecules are studied: 2-([2,2'-bithiophen]-5-yl)-ethan-1-aminium iodide (2TI) and 2-(3‴,4'-dimethyl-[2,2':5',2″:5″,2‴-quaterthiophen]-5-yl)-ethan-1-ammonium iodide (4TmI). We demonstrate that the speed of surface layer reconstruction under thermal stress can be controlled by the cation size and correlate these structural changes with the solar cell performance and stability. Devices treated with 2TI and 4TmI achieve PCEs over 21% and maintain their performance under thermal stress. Our findings demonstrate that thermal stability in PSCs can be achieved via the design engineering of passivation agents, offering a blueprint for developing next-generation passivation molecules.