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选择性激光烧结法制备的三维类螺旋立方晶格纳米多孔聚酰胺膜的特性

Characteristics of SLS-made 3D gyroid cubic lattice nanoporous polyamide membrane.

作者信息

Aldahash Saleh Ahmed, Uddin Mohammad Kashif

机构信息

Department of Mechanical and Industrial Engineering, College of Engineering, Majmaah University, Al-Majmaah, Saudi Arabia.

Department of Chemistry, College of Science, Al-Zulfi Campus, Majmaah University, Al-Majmaah, Saudi Arabia.

出版信息

PLoS One. 2025 Jun 9;20(6):e0324326. doi: 10.1371/journal.pone.0324326. eCollection 2025.

Abstract

A novel membrane can enhance the efficiency of various industrial processes and help address critical issues. Membranes made of polyamide are widely used and successful in membrane separation processes. This paper outlines a viable method for creating a three-dimensional gyroid nanostructured polyamide membrane through selective laser sintering. This method has easy setup, fast membrane preparation, no pollution, and low preparation cost. It is better than old-style solvent casting methods, which have inadequate management over the membrane structure. The prepared membrane was characterised using various essential techniques, and its properties were examined. The size of the membrane was 3 × 3 cm. A negative skewness value of -0.107 and a surface roughness of 22.4 nm indicate the presence of small peaks and high roughness. The CHN analysis shows the presence of 8.310% nitrogen, 42.100% carbon, 4.327% hydrogen, and 19.076% sulfur in the prepared membrane. The compressive strength of the membrane was calculated to be approximately 30 Mpa. A preliminary experiment on oil-water separation was conducted to address the growing issue of industrial oily wastewater. This study highlights the critical impact of surface properties on enhancing membrane performance, further solidifying their significance in membrane technology. This study provides insights for optimising membrane performance in future research.

摘要

一种新型膜可以提高各种工业过程的效率,并有助于解决关键问题。聚酰胺制成的膜在膜分离过程中被广泛使用且很成功。本文概述了一种通过选择性激光烧结制备三维螺旋状纳米结构聚酰胺膜的可行方法。该方法设置简便、膜制备速度快、无污染且制备成本低。它比老式的溶剂浇铸法更好,后者对膜结构的控制不足。使用各种基本技术对制备的膜进行了表征,并对其性能进行了检测。膜的尺寸为3×3厘米。负偏度值为-0.107以及表面粗糙度为22.4纳米表明存在小峰且粗糙度较高。CHN分析表明制备的膜中含有8.310%的氮、42.100%的碳、4.327%的氢和19.076%的硫。膜的抗压强度经计算约为30兆帕。为解决日益严重的工业含油废水问题,进行了油水分离的初步实验。本研究强调了表面性质对提高膜性能的关键影响,进一步巩固了它们在膜技术中的重要性。本研究为未来研究中优化膜性能提供了见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eea1/12148074/336e28fb7366/pone.0324326.g001.jpg

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