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用于增强室内空气处理的铂纳米颗粒尺寸改性二氧化钛纳米管阵列的可控沉积

Controlled deposition of Pt nanoparticle size modified TiO nanotubes arrays for enhanced indoor air treatment.

作者信息

Missaoui Khaoula, Hajjaji Mohamed Aziz, Assadi Amine Aymen, Hajjaji Anouar

机构信息

Laboratoire de Photovoltaïque, Centre de Recherches et des Technologies de l'Energie Technopole de Borj-Cédria, BP 95 Hammam-Lif 2050 Tunisia.

Ecole Nationale Supérieure de Chimie de Rennes, University of Rennes, CNRS, ISCR-UMR6226 Rennes 35000 France.

出版信息

RSC Adv. 2025 Jun 9;15(24):19489-19499. doi: 10.1039/d5ra01492a. eCollection 2025 Jun 4.

Abstract

Air pollution remains a significant global health challenge, with contaminants like volatile organic compounds (VOCs) and pathogenic bacteria serving as a major contributor. Titanium dioxide nanotubes (TiO-NTs) have emerged as promising materials for air purification, owing to their high surface area, photocatalytic activity, and stability. In this context, this study investigates the controlled electrodeposition of platinum (Pt) nanoparticles onto TiO-NTs to enhance their photocatalytic properties for indoor air treatment applications. By optimizing the Pt nanoparticle size and distribution, we aim to improve the degradation of VOCs and the inactivation of airborne bacteria. A series of Pt/TiO-NTs catalysts with varying Pt nanoparticle sizes were synthesized electrodeposition onto TiO-NTs fabricated anodization of titanium foil. The structural and optical properties of the modified nanotubes were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and photoluminescence (PL). The resulting materials exhibited enhanced photocatalytic degradation of VOCs and effective inactivation of () under visible light irradiation, attributable to the synergistic effects of Pt and TiO-NTs. Notably, catalysts decorated with smaller Pt nanoparticles (10-22 nm) demonstrated the highest photocatalytic activity, emphasizing the critical influence of nanoparticle size on performance.

摘要

空气污染仍然是一项重大的全球健康挑战,挥发性有机化合物(VOCs)和致病细菌等污染物是主要促成因素。二氧化钛纳米管(TiO-NTs)因其高表面积、光催化活性和稳定性,已成为空气净化的有前景材料。在此背景下,本研究探讨了将铂(Pt)纳米颗粒可控电沉积到TiO-NTs上,以增强其在室内空气处理应用中的光催化性能。通过优化Pt纳米颗粒的尺寸和分布,我们旨在提高VOCs的降解和空气中细菌的灭活。通过将不同Pt纳米颗粒尺寸的一系列Pt/TiO-NTs催化剂电沉积到通过钛箔阳极氧化制备的TiO-NTs上进行合成。使用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线光电子能谱(XPS)和光致发光(PL)对改性纳米管的结构和光学性质进行了表征。所得材料在可见光照射下表现出增强的VOCs光催化降解和对()的有效灭活,这归因于Pt和TiO-NTs的协同效应。值得注意的是,用较小Pt纳米颗粒(10 - 22 nm)修饰的催化剂表现出最高的光催化活性,强调了纳米颗粒尺寸对性能的关键影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9c4e/12147711/f9767bc056af/d5ra01492a-f1.jpg

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