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激光熔覆制备的Ni60/TiC和NbC复合涂层的耐蚀性与磨损行为

Corrosion Resistance and Wear Behavior of Ni60/TiC and NbC Composite Coatings Prepared by Laser Cladding.

作者信息

Zhan Qiang, Luo Fangyan, Huang Jiang, Wang Zhanshan, Ma Bin, Liu Chengpu

机构信息

Institute of Precision Optical Engineering, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China.

State Key Laboratory of Ultra-Intense Laser Science and Technology, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China.

出版信息

Materials (Basel). 2025 May 24;18(11):2459. doi: 10.3390/ma18112459.

Abstract

This research delves into the corrosion resistance and wear behavior of Ni60-based composite coatings strengthened by TiC and NbC particles, which are produced by laser cladding. Three distinct coatings were prepared: S1 (Ni60 + 20%TiC), S2 (Ni60 + 10%TiC + 10%NbC), and S3 (Ni60 + 20%NbC). Microstructural characterization revealed that the addition of TiC and NbC altered phase composition, inducing lattice distortion and promoting the formation of carbides such as CrC, NiC, and NbC. The S2 coating exhibited the highest average microhardness (1045 HV) due to synergistic grain refinement and homogeneous carbide dispersion. Wear resistance followed the order S2 > S3 > S1, attributed to the optimized balance of hard-phase distribution and reduced abrasive wear. Electrochemical tests in 3.5 wt% NaCl solution demonstrated superior corrosion resistance for S3, characterized by the lowest corrosion current density (1.732 × 10 A/cm) and a stable passivation film, facilitated by NbC-induced oxide formation. While S2 achieved peak mechanical performance, S3 excelled in corrosion resistance, highlighting the trade-off between carbide reinforcement and electrochemical stability. This work underscores the potential of tailoring dual-carbide systems in Ni60 coatings to enhance durability in harsh environments.

摘要

本研究深入探讨了通过激光熔覆制备的、由TiC和NbC颗粒增强的Ni60基复合涂层的耐腐蚀性和磨损行为。制备了三种不同的涂层:S1(Ni60 + 20%TiC)、S2(Ni60 + 10%TiC + 10%NbC)和S3(Ni60 + 20%NbC)。微观结构表征表明,TiC和NbC的添加改变了相组成,引起晶格畸变并促进了CrC、NiC和NbC等碳化物的形成。由于协同细化晶粒和均匀分布碳化物,S2涂层表现出最高的平均显微硬度(1045 HV)。耐磨性遵循S2 > S3 > S1的顺序,这归因于硬相分布的优化平衡和磨料磨损的减少。在3.5 wt% NaCl溶液中的电化学测试表明,S3具有优异的耐腐蚀性,其特征在于最低的腐蚀电流密度(1.732 × 10 A/cm)和由NbC诱导形成氧化物而促进的稳定钝化膜。虽然S2实现了峰值力学性能,但S3在耐腐蚀性方面表现出色,突出了碳化物增强与电化学稳定性之间的权衡。这项工作强调了在Ni60涂层中定制双碳化物体系以提高在恶劣环境下耐久性的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1bff/12156289/4250a0d589a2/materials-18-02459-g001.jpg

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