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以铜尾矿为细集料制备水泥砂浆的配合比优化及微观机理研究

Optimization of the Proportioning and Microscopic Mechanism Study of Cement Mortar Prepared with Copper Tailings as Fine Aggregate.

作者信息

Li Haizhou, Zhang Lu, Liu Jianping, Chu Daozhong, Ren Jiaolong

机构信息

School of Resources and Environmental Engineering, Shandong University of Technology, Zibo 255000, China.

Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials of Ministry of Education, Shandong University, Jinan 250061, China.

出版信息

Materials (Basel). 2025 May 30;18(11):2569. doi: 10.3390/ma18112569.

Abstract

To address the low resource utilization of copper tailings and high environmental impact of conventional river sand, this study innovatively integrates Box-Behnken design (BBD) with fractal theory to systematically investigate the performance optimization mechanisms of cement mortar incorporating copper tailings sand. A three-factor interaction model was developed through BBD experimental design, considering water-cement ratio (0.38-0.48), replacement ratio (10-30%), and binder-sand ratio (0.3-0.4), to elucidate the macroscopic performance evolution under multiparameter coupling effects. Fractal dimension analysis was employed to quantitatively characterize microstructural evolution. Experimental results demonstrate that the optimal parameters (water-cement ratio: 0.43, replacement ratio: 20%, binder-sand ratio: 0.35) yield superior performance, with 28-day compressive/flexural strengths reaching 61.88/7.14 MPa (12.3%/9.8% enhancement over the control group), and sulfate attack resistance showing 0.74% mass loss after 30 cycles. Microstructural analysis reveals reduced fractal dimension (D = 2.31) in copper tailings-modified specimens, indicating improved pore structure homogeneity. The enhanced performance is attributed to synergistic effects of micro-aggregate filling and pozzolanic reaction-driven C-S-H gel densification. This research establishes a novel multiscale methodology overcoming the limitations of conventional single-factor analysis, providing theoretical and technical support for high-value utilization of industrial solid wastes in construction materials.

摘要

为了解决铜尾矿资源利用率低以及传统河砂对环境影响大的问题,本研究创新性地将Box-Behnken设计(BBD)与分形理论相结合,系统地研究了掺入铜尾矿砂的水泥砂浆的性能优化机制。通过BBD实验设计建立了一个三因素相互作用模型,考虑水灰比(0.38 - 0.48)、替代率(10 - 30%)和胶凝材料与砂比(0.3 - 0.4),以阐明多参数耦合效应下的宏观性能演变。采用分形维数分析对微观结构演变进行定量表征。实验结果表明,最佳参数(水灰比:0.43,替代率:20%,胶凝材料与砂比:0.35)产生了优异的性能,28天抗压强度/抗折强度达到61.88/7.14 MPa(比对照组提高12.3%/9.8%),30次循环后的抗硫酸盐侵蚀性能质量损失为0.74%。微观结构分析表明,铜尾矿改性试件的分形维数降低(D = 2.31),表明孔隙结构均匀性得到改善。性能的提高归因于微集料填充和火山灰反应驱动的C-S-H凝胶致密化的协同效应。本研究建立了一种新颖的多尺度方法,克服了传统单因素分析的局限性,为建筑材料中工业固体废物的高值利用提供了理论和技术支持。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/edb5/12155830/d28c5dede306/materials-18-02569-g001.jpg

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