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采用两阶段法生产的TPS/PA12复合材料的选定性能。

Selected Properties of a TPS/PA12 Composite Material Produced in a Two-Stage Method.

作者信息

Tomaszewska-Ciosk Ewa, Zdybel Ewa, Kapelko-Żeberska Małgorzata, Anwajler Beata

机构信息

Department of Food Storage and Technology, Wroclaw University of Environmental and Life Sciences, 25 Norwida Street, 50-375 Wroclaw, Poland.

Department of Energy Conversion Engineering, Faculty of Mechanical and Power Engineering, Wroclaw University of Science and Technology, 27 Wybrzeze Wyspianskiego Street, 50-370 Wroclaw, Poland.

出版信息

Polymers (Basel). 2025 May 29;17(11):1517. doi: 10.3390/polym17111517.

Abstract

The world economy is struggling with the increasing pollution of the natural environment with non-biodegradable synthetic polymers produced from petroleum products. This fact has prompted research on the use of natural renewable polymers. Starch is one of the polymers that has already been used as an additive to synthetic polymers; however, its use is associated with a problem arising from the incompatibility of hydrophilic starch with hydrophobic synthetic polymers. For these reasons, other authors have not used more than 20% of the starch component in synthetic materials. In this work, a research hypothesis was put forward that the starch content can be increased in the polymer material. Pre-extrusion was used before the final material molding process. Pre-extrusion improved the phase dispersion of the synthetic polymer blended with starch. To produce the molds, the polyamide and starch blends were subjected to the processes of extrusion, milling, and pressing. The molded samples containing polyamide and starch were obtained with a starch component content of 50, 70, and 90%. The obtained homogeneous material was determined in terms of its water resistance and mechanical properties. The test results showed that increasing the starch content in the produced material, increased its susceptibility to water, and worsened its strength properties. However, these negative effects were not as large as expected, and in some cases were even statistically insignificant. The addition of 70% of the starch component allowed for the production of a composite material with satisfactory mechanical properties.

摘要

世界经济正面临着一个难题,即由石油产品生产的不可生物降解合成聚合物对自然环境造成的污染日益严重。这一事实促使人们对天然可再生聚合物的使用展开研究。淀粉是已被用作合成聚合物添加剂的聚合物之一;然而,其使用存在一个问题,即亲水性淀粉与疏水性合成聚合物不相容。基于这些原因,其他作者在合成材料中使用的淀粉成分不超过20%。在这项工作中,提出了一个研究假设,即聚合物材料中的淀粉含量可以增加。在最终材料成型工艺之前进行了预挤出。预挤出改善了与淀粉共混的合成聚合物的相分散。为了制作模具,将聚酰胺和淀粉共混物进行挤出、研磨和压制工艺。获得了含有聚酰胺和淀粉的模塑样品,其淀粉成分含量分别为50%、70%和90%。对所得的均质材料进行了耐水性和机械性能方面的测定。测试结果表明,所生产材料中淀粉含量的增加,使其对水的敏感性增加,强度性能变差。然而,这些负面影响并不像预期的那么大,在某些情况下甚至在统计学上不显著。添加70%的淀粉成分能够生产出具有令人满意机械性能的复合材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c1d7/12157777/45a2d4762c06/polymers-17-01517-g001.jpg

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