• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

改性纳米晶纤维素增强水性环氧涂料性能研究

Research on the Performance of Modified Nanocrystalline Cellulose Reinforced Waterborne Epoxy Coatings.

作者信息

Kang Lei, Zeng Qiao, Fan Jiang, Dang Xinzhe, Yan Bo, Wang Yongwei, Guo Xingpeng

机构信息

School of Surveying & Testing, Shaanxi Railway Institute, Weinan, Shaanxi 714000, China.

School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China.

出版信息

ACS Omega. 2025 Jun 3;10(23):24367-24381. doi: 10.1021/acsomega.5c00478. eCollection 2025 Jun 17.

DOI:10.1021/acsomega.5c00478
PMID:40547683
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12177591/
Abstract

This study addresses the critical challenges of long-term protection and mechanical stability in waterborne epoxy resin (WEP) coatings by developing composite systems reinforced with modified nanocrystalline cellulose (NCC). Through surface functionalization of NCC using hexadecyltrimethoxysilane (HDTMS) and -[3-(trimethoxysilyl)-propyl]-ethylenediamine (TMPEDA), we synthesized Si-NCC/WEP coatings with enhanced interfacial compatibility and tailored physicochemical properties. Comprehensive characterization via FTIR, AFM, and EIS revealed that the 1% Si-NCC/WEP coating exhibited optimal performance, achieving a 251% increase in Young's modulus (6.95 GPa vs 2.77 GPa for pure WEP) and superior corrosion resistance, as evidenced by a two-order-of-magnitude higher impedance modulus (1.55 × 10 Ω·cm) in neutral 3.5% NaCl solution compared to unmodified WEP. While alkaline and neutral environments demonstrated remarkable barrier stability (retaining 1.80 × 10 Ω·cm after 30 day immersion), acidic conditions (pH = 1) revealed limitations due to NCC's hydrolytic instability. This work establishes a green nanocomposite design paradigm for durable protective coatings, offering actionable insights for industrial corrosion mitigation strategies.

摘要

本研究通过开发用改性纳米晶纤维素（NCC）增强的复合体系，解决了水性环氧树脂（WEP）涂料长期保护和机械稳定性方面的关键挑战。通过使用十六烷基三甲氧基硅烷（HDTMS）和-[3-(三甲氧基甲硅烷基)丙基]乙二胺（TMPEDA）对NCC进行表面功能化，我们合成了具有增强界面相容性和定制物理化学性质的Si-NCC/WEP涂料。通过傅里叶变换红外光谱（FTIR）、原子力显微镜（AFM）和电化学阻抗谱（EIS）进行的综合表征表明，1%的Si-NCC/WEP涂料表现出最佳性能，杨氏模量提高了251%（纯WEP为2.77 GPa，Si-NCC/WEP为6.95 GPa），并且具有优异的耐腐蚀性，在中性3.5% NaCl溶液中的阻抗模量比未改性的WEP高出两个数量级（1.55×10 Ω·cm）。虽然碱性和中性环境表现出显著的阻隔稳定性（浸泡30天后保持在1.80×10 Ω·cm），但酸性条件（pH = 1）由于NCC的水解不稳定性而显示出局限性。这项工作建立了一种用于耐用防护涂层的绿色纳米复合材料设计范例，为工业腐蚀缓解策略提供了可行的见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/e935c215aa70/ao5c00478_0012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/dd86f67899db/ao5c00478_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/3ab5735d34a9/ao5c00478_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/27b450e5b1cf/ao5c00478_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/43b9d1566119/ao5c00478_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/8cb2e07a9312/ao5c00478_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/30c273407239/ao5c00478_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/3ae49675c029/ao5c00478_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/44d67a7d5ee1/ao5c00478_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/563ea7ae996f/ao5c00478_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/c8c9e9747c69/ao5c00478_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/7cb3110e5175/ao5c00478_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/e935c215aa70/ao5c00478_0012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/dd86f67899db/ao5c00478_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/3ab5735d34a9/ao5c00478_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/27b450e5b1cf/ao5c00478_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/43b9d1566119/ao5c00478_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/8cb2e07a9312/ao5c00478_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/30c273407239/ao5c00478_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/3ae49675c029/ao5c00478_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/44d67a7d5ee1/ao5c00478_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/563ea7ae996f/ao5c00478_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/c8c9e9747c69/ao5c00478_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/7cb3110e5175/ao5c00478_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f998/12177591/e935c215aa70/ao5c00478_0012.jpg

相似文献

1
Research on the Performance of Modified Nanocrystalline Cellulose Reinforced Waterborne Epoxy Coatings.改性纳米晶纤维素增强水性环氧涂料性能研究
ACS Omega. 2025 Jun 3;10(23):24367-24381. doi: 10.1021/acsomega.5c00478. eCollection 2025 Jun 17.
2
Enhanced corrosion resistance of zinc phosphate coatings on mild steel through incorporation of nanocrystalline CeO and CeO-CuO nanocomposite.通过掺入纳米晶CeO和CeO-CuO纳米复合材料提高低碳钢上磷酸锌涂层的耐腐蚀性。
RSC Adv. 2025 Jun 20;15(26):20916-20934. doi: 10.1039/d5ra02800k. eCollection 2025 Jun 16.
3
Cellulose nanocrystals-reinforced waterborne epoxy coatings with enhanced corrosion resistance for steel.纤维素纳米晶增强型水性环氧涂层，提高了钢的耐腐蚀性。
Int J Biol Macromol. 2024 Feb;257(Pt 2):128755. doi: 10.1016/j.ijbiomac.2023.128755. Epub 2023 Dec 12.
4
TiO Nanocontainers Coconstructed Using Polymers and Corrosion Inhibitors for Anticorrosion Reinforcement of Waterborne Epoxy Coatings.使用聚合物和缓蚀剂共构建的TiO纳米容器用于水性环氧涂料的防腐增强
ACS Appl Mater Interfaces. 2023 Nov 15;15(45):52971-52983. doi: 10.1021/acsami.3c12194. Epub 2023 Nov 1.
5
Atraumatic restorative treatment versus conventional restorative treatment for managing dental caries.非创伤性修复治疗与传统修复治疗在龋病管理中的比较
Cochrane Database Syst Rev. 2017 Dec 28;12(12):CD008072. doi: 10.1002/14651858.CD008072.pub2.
6
Novel Lignin-Functionalized Waterborne Epoxy Composite Coatings with Excellent Anti-Aging, UV Resistance, and Interfacial Anti-Corrosion Performance.具有优异抗老化、抗紫外线和界面防腐性能的新型木质素功能化水性环氧复合涂料
Small. 2024 Jul;20(28):e2312085. doi: 10.1002/smll.202312085. Epub 2024 Feb 11.
7
A study on the thermodynamic performance of nano-silicide filled epoxy resin composite materials.纳米硅化物填充环氧树脂复合材料的热力学性能研究
Phys Chem Chem Phys. 2025 Jun 18;27(24):13103-13115. doi: 10.1039/d5cp01471a.
8
Synergistically assembled graphene/ZnO composite to enhance anticorrosion performance of waterborne epoxy coatings.协同组装的石墨烯/氧化锌复合材料用于增强水性环氧涂料的防腐性能。
RSC Adv. 2022 Mar 22;12(15):9069-9076. doi: 10.1039/d2ra00959e. eCollection 2022 Mar 21.
9
Sealants for preventing dental caries in primary teeth.窝沟封闭剂预防儿童乳牙龋齿。
Cochrane Database Syst Rev. 2022 Feb 11;2(2):CD012981. doi: 10.1002/14651858.CD012981.pub2.
10
Interventions for preventing occupational irritant hand dermatitis.预防职业性刺激性手部皮炎的干预措施。
Cochrane Database Syst Rev. 2018 Apr 30;4(4):CD004414. doi: 10.1002/14651858.CD004414.pub3.

引用本文的文献

1
Improvement of anti-swelling property and anticorrosion performance of epoxy coatings by the introduction of nanocrystalline cellulose composite.通过引入纳米晶纤维素复合材料提高环氧涂层的抗膨胀性能和防腐性能。
Sci Rep. 2025 Jul 29;15(1):27706. doi: 10.1038/s41598-025-13057-5.

本文引用的文献

1
Nanocellulose Grades with Different Morphologies and Surface Modification as Additives for Waterborne Epoxy Coatings.具有不同形态和表面改性的纳米纤维素等级作为水性环氧涂料的添加剂
Polymers (Basel). 2024 Apr 14;16(8):1095. doi: 10.3390/polym16081095.
2
Review on Soil Corrosion and Protection of Grounding Grids.接地网的土壤腐蚀与防护综述
Materials (Basel). 2024 Jan 20;17(2):507. doi: 10.3390/ma17020507.
3
Cellulose nanocrystals-reinforced waterborne epoxy coatings with enhanced corrosion resistance for steel.纤维素纳米晶增强型水性环氧涂层，提高了钢的耐腐蚀性。
Int J Biol Macromol. 2024 Feb;257(Pt 2):128755. doi: 10.1016/j.ijbiomac.2023.128755. Epub 2023 Dec 12.
4
Highly Modified Cellulose Nanocrystals and Formation of Epoxy-Nanocrystalline Cellulose (CNC) Nanocomposites.高度改性的纤维素纳米晶体及环氧-纳米晶纤维素（CNC）纳米复合材料的形成
ACS Appl Mater Interfaces. 2016 Oct 19;8(41):28086-28095. doi: 10.1021/acsami.6b09852. Epub 2016 Oct 10.
5
Adhesion forces between AFM tips and superficial dentin surfaces.原子力显微镜针尖与表面牙本质之间的黏附力。
J Colloid Interface Sci. 2012 Jun 15;376(1):262-8. doi: 10.1016/j.jcis.2012.03.013. Epub 2012 Mar 14.