Lozon Cara, Cornet Antoine, Reculusa Stéphane, Garrigue Patrick, Kuhn Alexander, Salinas Gerardo
Univ. Bordeaux, CNRS UMR 5255, Bordeaux INP, Site ENSMAC 33607 Pessac France
Chem Sci. 2025 Jun 16. doi: 10.1039/d5sc00911a.
Magnetically-driven dynamic systems have gained considerable attention in multiple applications ranging from cargo delivery to environmental remediation. However, they commonly require ferromagnetic components or sophisticated electromagnetic equipment. In this work we take advantage of the synergy between exogenous bipolar electrochemistry and the classic geometry of a solenoid in order to design an externally driven chemo-electromagnet. By wirelessly triggering redox reactions at each extremity of a solenoid-shaped swimmer, the generated electric current follows the helical path of the coil, thus generating a concentric magnetic field in its center. Such an externally induced redox current generates magnetic fields in the range of μT which are proportional to the applied electric field. The on-board chemically induced magnetic dipole allows the swimmers to perform rotational motion in the presence of an external magnetic field, without the use of traditional ferromagnetic materials. Additionally, when exposing these devices to alternating electric and magnetic fields, well-defined oscillatory motion is produced, demonstrating the efficient electromagnetic control of the dynamic displacement. This opens up novel and, so far, unexplored possibilities for localized chemical conversion magnetically-driven "chemistry on-the-fly".
磁驱动动态系统在从货物运输到环境修复等多种应用中受到了广泛关注。然而,它们通常需要铁磁部件或复杂的电磁设备。在这项工作中,我们利用外源双极电化学与螺线管经典几何形状之间的协同作用,设计了一种外部驱动的化学电磁体。通过无线触发螺线管形状游动器两端的氧化还原反应,产生的电流沿着线圈的螺旋路径流动,从而在其中心产生同心磁场。这种外部感应的氧化还原电流产生的磁场在微特斯拉范围内,与施加的电场成正比。板载化学诱导磁偶极使游动器在外部磁场存在的情况下能够进行旋转运动,而无需使用传统的铁磁材料。此外,当将这些装置暴露于交变电场和磁场时,会产生明确的振荡运动,证明了对动态位移的有效电磁控制。这为局部化学转化——磁驱动的“即时化学”开辟了新的、迄今为止尚未探索的可能性。