High-Performance Vacuum-Free Processed Organic Solar Cells with Gallium-Based Liquid Metal Top Electrodes.

Conventional fabrication of high-efficiency organic solar cells (OSCs) predominantly relies on vacuum-evaporated metal top electrodes such as Ag and Al, which hinder large-scale industrial production. Gallium-based liquid metals (GaLMs), particularly the eutectic gallium-indium alloy (EGaIn), represent promising candidates to conventional vacuum-evaporated metal top electrodes due to their excellent printability and high electrical conductivity. In this study, we fabricated vacuum-free OSCs based on GaLM electrodes (Ga, EGaIn, and Galinstan) and analyzed the device performances. Rigid devices with EGaIn electrodes achieved a champion power conversion efficiency (PCE) of 15.6%. Remarkably, all-solution-processed ultrathin flexible devices employing silver nanowire (AgNW) bottom electrodes in combination with EGaIn top electrodes achieved a PCE of 13.8% while maintaining 83.4% of their initial performance after 100 compression-tension cycles (at 30% strain). This work highlights the potential of GaLMs as cost-effective, scalable, and high-performance top electrodes for next-generation flexible photovoltaic devices, paving the way for their industrial adoption.