Hou Jiangyan, Wang Tianyi, Wang Yao, Feng Xinhao, Liu Xinyou
College of Furnishing and Industrial Design, Nanjing Forestry University, Str. Longpan No. 159, Nanjing 210037, China.
Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China.
Polymers (Basel). 2025 Jun 7;17(12):1596. doi: 10.3390/polym17121596.
Chinese lacquer, a historically significant bio-based coating, has garnered increasing attention in sustainable materials research due to its outstanding corrosion resistance, thermal stability, and environmental friendliness. Its curing process relies on the laccase-catalyzed oxidation and polymerization of urushiol to form a dense lacquer film. However, the stringent temperature and humidity requirements (20-30 °C, 70-80% humidity) and a curing period that can extend over several weeks severely constrain its industrial application. Recent studies have significantly enhanced the curing efficiency through strategies such as pre-polymerization control, metal ion catalysis (e.g., Cu reducing drying time to just one day), and nanomaterial modification (e.g., nano-AlO increasing film hardness to 6H). Nevertheless, challenges remain, including the sensitivity of laccase activity to environmental fluctuations, the trade-off between accelerated curing and film performance, and issues related to toxic pigments and VOC emissions. Future developments should integrate enzyme engineering (e.g., directed evolution to broaden laccase tolerance), intelligent catalytic systems (e.g., photo-enzyme synergy), and green technologies (e.g., UV curing), complemented by multiscale modeling and circular design strategies, to drive the innovative applications of Chinese lacquer in high-end fields such as aerospace sealing and cultural heritage preservation.
中国漆是一种具有历史意义的生物基涂料,因其出色的耐腐蚀性、热稳定性和环境友好性,在可持续材料研究中受到越来越多的关注。其固化过程依赖于漆酶催化漆酚的氧化和聚合,以形成致密的漆膜。然而,严格的温度和湿度要求(20-30°C,70-80%湿度)以及可能延长数周的固化期严重限制了其工业应用。最近的研究通过预聚合控制、金属离子催化(如铜将干燥时间缩短至仅一天)和纳米材料改性(如纳米氧化铝将漆膜硬度提高到6H)等策略显著提高了固化效率。尽管如此,挑战依然存在,包括漆酶活性对环境波动的敏感性、加速固化与漆膜性能之间的权衡,以及与有毒颜料和挥发性有机化合物排放相关的问题。未来的发展应整合酶工程(如定向进化以拓宽漆酶耐受性)、智能催化系统(如光酶协同作用)和绿色技术(如紫外线固化),并辅以多尺度建模和循环设计策略,以推动中国漆在航空航天密封和文化遗产保护等高端领域的创新应用。