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用于从水中选择性去除镉(II)和铅(II)的高效席夫碱配体。

Efficient Schiff base ligand for selective Cd(ii) and Pb(ii) removal from water.

作者信息

Mubark Amal E, El-Gamasy Sabreen M, Masoud Ahmed M, El-Zahhar Adel A, Alghamdi Majed M, Taha Mohamed H, Hassanein Taha F

机构信息

Nuclear Materials Authority P.O. Box 530, El Maddi Cairo Egypt

Chemistry Department, Faculty of Science, Menoufia University Shebin El-Koam 00123 Egypt.

出版信息

RSC Adv. 2025 Jun 27;15(27):21987-22005. doi: 10.1039/d5ra03053f. eCollection 2025 Jun 23.

Abstract

This study reports the development and evaluation of a novel Schiff base ligand, 2-(()-(4-aminophenylimino)methyl)benzoic acid, for the efficient removal of lead(ii) and cadmium(ii) from aqueous solutions. The ligand was synthesized a simple condensation route and characterized to confirm its structural and functional properties. Batch adsorption experiments were performed to investigate the effects of pH, temperature, metal ion concentration, contact time, and competing ions. The ligand exhibited high sorption capacities-84.0 mg g for Pb(ii) and 71.0 mg g for Cd(ii)-with optimal performance at pH 6.0. Adsorption kinetics followed a pseudo-second-order model, while equilibrium data fit well with the Langmuir and Sips isotherms, indicating chemisorption and monolayer coverage. Thermodynamic analysis confirmed the spontaneous and exothermic nature of the process. The ligand demonstrated excellent reusability over multiple cycles and retained strong selectivity in the presence of competing ions and in real wastewater. These findings suggest that the synthesized ligand is a promising and sustainable candidate for heavy metal remediation in water treatment applications.

摘要

本研究报告了一种新型席夫碱配体2-((()-(4-氨基苯基亚氨基)甲基)苯甲酸的开发与评估,该配体用于从水溶液中高效去除铅(ii)和镉(ii)。通过简单的缩合路线合成了该配体,并对其进行了表征以确认其结构和功能特性。进行了批量吸附实验,以研究pH值、温度、金属离子浓度、接触时间和竞争离子的影响。该配体表现出高吸附容量——对Pb(ii)为84.0 mg/g,对Cd(ii)为71.0 mg/g——在pH 6.0时性能最佳。吸附动力学遵循准二级模型,而平衡数据与朗缪尔等温线和西普斯等温线拟合良好,表明发生了化学吸附和单层覆盖。热力学分析证实了该过程的自发性和放热性质。该配体在多个循环中表现出优异的可重复使用性,并且在存在竞争离子和实际废水中仍保持较强的选择性。这些发现表明,合成的配体是水处理应用中重金属修复的一个有前景的可持续候选物。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9a91/12203165/48de90877f1a/d5ra03053f-f1.jpg

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