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棕榈纤维与纳米填料增强环氧纳米复合材料热性能的优化

Optimization of thermal properties of palm fiber and nanofillers reinforced epoxy nanocomposite.

作者信息

Thirupathi Suresh, Gopalan Venkatachalam, Mallichetty Elango

机构信息

School of Mechanical Engineering, Vellore Institute of Technology, Chennai, Tamilnadu, 600127, India.

Centre for Advanced Materials and Innovative Technologies, Vellore Institute of Technology, Chennai, Tamilnadu, 600127, India.

出版信息

Sci Rep. 2025 Jul 1;15(1):21582. doi: 10.1038/s41598-025-03474-x.

Abstract

In recent times, the growing economic concerns and the rising cost of synthetic fibers have shifted focus to natural fiber reinforced composites, which are evident in the current literature. It is important to understand the thermal properties of these materials for functional applications. This study investigates the thermal conductivity of epoxy composites reinforced with sodium hydroxide (NaOH)-treated palm fruit fiber, a rarely used natural resource, with the addition of nanofillers, multi-walled carbon nanotubes, hexagonal boron nitride (h-BN), and aluminium oxide (AlO) used at 1 wt.%. The hand layup method is used to fabricate nanocomposites with varying palm fiber content (1-5 wt.%) with mesh size (75-225 µm) and nanofiller. The prepared nanocomposite samples are measured for thermal conductivity. SEM analysis manifests that alkali treatment increases the surface morphology of fiber as cleansed from impurities, which in turn increases bonding with the epoxy matrix at the interface. RSM was used to optimize these parameters, specifically the Box-Behnken Design (BBD) of RSM, with ANOVA analysis using Design-Expert 13 software to generate a strong regression model. The results demonstrate a maximum thermal conductivity of 1.54 W/m·K with 1 wt.% of palm fiber, 75 µm mesh size and 1% h-BN. This research emphasizes the promise of epoxy composites based on palm fibers for applications in thermal management in areas such as electronic devices, and circuit boards while contributing to the development of novel and efficient material solutions.

摘要

近年来,日益增长的经济担忧和合成纤维成本的上升使人们将注意力转向了天然纤维增强复合材料,这在当前的文献中很明显。了解这些材料的热性能对于功能应用很重要。本研究调查了用氢氧化钠(NaOH)处理过的棕榈果纤维增强的环氧复合材料的热导率,棕榈果纤维是一种很少使用的自然资源,并添加了纳米填料、多壁碳纳米管、六方氮化硼(h-BN)和氧化铝(AlO),添加量为1 wt.%。采用手糊法制备了具有不同棕榈纤维含量(1-5 wt.%)、网目尺寸(75-225 µm)和纳米填料的纳米复合材料。对制备的纳米复合材料样品进行热导率测量。扫描电子显微镜分析表明,碱处理增加了纤维的表面形态,去除了杂质,进而增加了与环氧基体在界面处的结合。采用响应曲面法(RSM)对这些参数进行优化,特别是RSM的Box-Behnken设计(BBD),并使用Design-Expert 13软件进行方差分析(ANOVA)以生成强大的回归模型。结果表明,当棕榈纤维含量为1 wt.%、网目尺寸为75 µm且h-BN含量为1%时,热导率最高可达1.54 W/m·K。本研究强调了基于棕榈纤维的环氧复合材料在电子设备和电路板等热管理领域应用的前景,同时为新型高效材料解决方案的开发做出了贡献。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e0e0/12216161/59e99be6d19c/41598_2025_3474_Fig1_HTML.jpg

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