Rodrigo Loshini, Munaweera Imalka, Perera Pamoda Thavish
Department of Chemistry, University of Sri Jayewardenepura Nugegoda 10250 Sri Lanka
Research and development division, Panam Biotech Pvt (Ltd) Homagama 10200 Sri Lanka.
RSC Adv. 2025 Jul 2;15(28):22587-22604. doi: 10.1039/d5ra03488d. eCollection 2025 Jun 30.
Rising food demand due to population growth and the low nutrient use efficiency (NUE) of conventional fertilizers necessitate environmentally friendly, effective agrochemical delivery systems. Hydrogels are innovative materials, and an integrated hydrogel formulation encapsulated with zinc oxide nanoparticles (ZnO NPs), potassium chloride and naphthalene acetic acid (NAA) was synthesized in this study to increase the flowering and crop yield of the short-term crop chili. ZnO NPs were synthesized the co-precipitation method and characterized XRD, SEM and FTIR techniques. The synthesized hydrogels were characterized using SEM and FTIR techniques. The swelling capacity of the hydrogels peaked at 202.04% on day 14, and they exhibited biodegradation by day 20, with a weight loss of 99.98%. Biodegradation findings were corroborated by optical microscopy pictures. Atomic absorption spectrometry was used to study the release of potassium and zinc nutrients from the hydrogels on days 1, 7, 14, and 21, suggesting the slow-release behavior of the hydrogels. UV-VIS spectrophotometry was used to study the NAA hormone, which revealed a higher encapsulation efficiency of 92.53% with a sustained, slow-release profile over a 21-day period. The exponential phase of the NAA-release profile matched well with the Higuchi model ( = 0.97). The parameters plant height, number of branches, flowers, pods and yield at first plucking were statistically analyzed using the analysis of variance (ANOVA), and significant differences between each sample were analyzed using Tukey pairwise comparison at a significance level of 0.05. Significant enhancements observed in flowering and yield were attributed to the synergistic effect of the encapsulated agrochemicals in the hydrogels. The ability to biodegrade and improve NUE positions this integrated hydrogel formulation as a sustainable alternative for modern agriculture.
由于人口增长导致的粮食需求上升以及传统肥料的养分利用效率低下,需要环境友好、有效的农用化学品输送系统。水凝胶是创新材料,本研究合成了一种包裹有氧化锌纳米颗粒(ZnO NPs)、氯化钾和萘乙酸(NAA)的集成水凝胶配方,以提高短期作物辣椒的开花率和作物产量。采用共沉淀法合成ZnO NPs,并通过XRD、SEM和FTIR技术对其进行表征。使用SEM和FTIR技术对合成的水凝胶进行表征。水凝胶的溶胀能力在第14天达到峰值202.04%,到第20天它们表现出生物降解,重量损失99.98%。光学显微镜照片证实了生物降解结果。采用原子吸收光谱法研究了水凝胶在第1、7、14和21天钾和锌养分的释放情况,表明水凝胶具有缓释行为。采用紫外可见分光光度法研究NAA激素,结果显示其包封效率较高,为92.53%,在21天内具有持续、缓释的特性。NAA释放曲线的指数阶段与Higuchi模型拟合良好( = 0.97)。使用方差分析(ANOVA)对首次采摘时的株高、分枝数、花数、荚数和产量等参数进行统计分析,并使用Tukey成对比较在显著性水平0.05下分析每个样本之间的显著差异。观察到的开花和产量的显著提高归因于水凝胶中包裹的农用化学品的协同作用。生物降解能力和提高养分利用效率的能力使这种集成水凝胶配方成为现代农业的可持续替代品。
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