Zhu Kangxin, Ma Chaoliang, Song Lvfu, Jin Lizheng, Wang Jinpeng, Wei Junjie, Wu Yitian, Zheng Xin, Wu Sai, Pang Yajun, Shen Zhehong, Chen Hao
College of Chemistry and Materials Engineering, Zhejiang Provincial Collaborative Innovation Center for Bamboo Resources and High-Efficiency Utilization, National Engineering and Technology Research Center of Wood-based Resources Comprehensive Utilization, Key Laboratory of Wood Science and Technology of Zhejiang Province, Zhejiang A&F University, Hangzhou 311300, PR China.
College of Chemistry and Materials Engineering, Zhejiang Provincial Collaborative Innovation Center for Bamboo Resources and High-Efficiency Utilization, National Engineering and Technology Research Center of Wood-based Resources Comprehensive Utilization, Key Laboratory of Wood Science and Technology of Zhejiang Province, Zhejiang A&F University, Hangzhou 311300, PR China.
J Colloid Interface Sci. 2025 Dec;699(Pt 2):138298. doi: 10.1016/j.jcis.2025.138298. Epub 2025 Jun 27.
Although wood-based evaporative materials showcase promising prospects for desalination by interfacial solar evaporation, the persistence of salt and biofouling problems still challenges this process. The present work introduces an algae-resistant suspended evaporator with semiconductor-enhanced anti-algae properties, ensuring high evaporation activity while preventing algae contamination and salt accumulation. Unlike pure wood evaporative materials that have noticeable algae attachment in algae-growing environments, and evaporative materials with a hydrophobic light-absorbing layer but no semiconductors that still exhibit algae attachment at the microscopic level, the as-designed anti-algae evaporator demonstrates minimal algae presence in both macroscopically and microscopically. More impressively, benefiting from the anti-algae agent, the hydrophobic properties of the suspended evaporative material, which are responsible for guaranteeing high activity and durability, are not destroyed, exhibiting better stability. As a result, the evaporation rate drops from 1.62 to 1.34 kg m h without the semiconductor anti-algae agent, and the light-vapor conversion efficiency is drastically reduced from 90.91 % to 73.83 % accordingly. Comparatively, the algae-resistant evaporator can maintain an evaporation rate of 1.54 kg m h and an efficiency of 85.12 %, with a retention of evaporation rate up to 95.65 %, showcasing excellent long-term performance. This work offers a promising approach for developing stable, algae-resistant evaporators, advancing solar-powered desalination using biomass materials.
尽管木质蒸发材料在界面太阳能蒸发海水淡化方面展现出了广阔前景,但盐分和生物污垢问题的持续存在仍对这一过程构成挑战。目前的工作引入了一种具有半导体增强抗藻性能的抗藻悬浮蒸发器,既能确保高蒸发活性,又能防止藻类污染和盐分积累。与在藻类生长环境中会有明显藻类附着的纯木质蒸发材料不同,以及与具有疏水吸光层但没有半导体且在微观层面仍会出现藻类附着的蒸发材料不同,所设计的抗藻蒸发器在宏观和微观层面的藻类存在都极少。更令人印象深刻的是,受益于抗藻剂,负责保证高活性和耐久性的悬浮蒸发材料的疏水性能并未被破坏,表现出更好的稳定性。结果,没有半导体抗藻剂时,蒸发速率从1.62千克·平方米·小时降至1.34千克·平方米·小时,光蒸汽转换效率相应地从90.91%大幅降至73.83%。相比之下,抗藻蒸发器可保持1.54千克·平方米·小时的蒸发速率和85.12%的效率,蒸发速率保留率高达95.65%,展现出优异的长期性能。这项工作为开发稳定的抗藻蒸发器提供了一种有前景的方法,推动了利用生物质材料的太阳能海水淡化。