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电石渣-脱碱赤泥与固体废弃物复合材料在道路材料中的稳定性及适用性研究

Study on Stability and Applicability of Calcium Carbide Slag-Dealkalized Red Mud and Solid Waste Composite Materials in Road Materials.

作者信息

Wang Wentong, Wang Shuqian, Cheng Yu, Jia Meng, Gao Jianyang

机构信息

College of Transportation, Shandong University of Science and Technology, Qingdao 266590, China.

CHALCO Shandong Co. Ltd., Zibo 255052, China.

出版信息

Materials (Basel). 2025 Jul 2;18(13):3140. doi: 10.3390/ma18133140.

Abstract

The storage of highly alkaline red mud (RM) consumes land and threatens the environment, making its reuse crucial. The study used calcium carbide slag to dealkalize it, and analyzed the changes in mineral particles in RM using a CT scan. It then evaluated the stabilization effects of different materials and explored the mechanism of RM solidification through analysis of micro-mechanisms. The results showed that after dealkalization with CCS, RM particles form more agglomerates and the overall structure becomes more compact, and the Na content in RM decreased from 10.44 wt% to 0.86 wt%. After treatment with stabilization materials, the mechanical strength of low-alkalinity RM was greatly improved, and the stabilization effect of composite slag was the best. When the partial replacement ratio was 12%, the 28 d compressive strength was 4.51 MPa. After soaking in water for one day and night, the strength decreased by 24.3%, which had good stability. This study found that the strength gains were mainly due to crystal substances like CaAlO and non-crystalline substances such as C-S-H filling pores and wrapping particles. This study provides a new method for RM stabilization and promotes the utilization of industrial by-products.

摘要

高碱性赤泥(RM)的储存占用土地并威胁环境,因此其再利用至关重要。该研究使用电石渣对其进行脱碱处理,并通过CT扫描分析RM中矿物颗粒的变化。然后评估了不同材料的稳定化效果,并通过微观机制分析探索了RM固化的机理。结果表明,用CCS脱碱后,RM颗粒形成更多团聚体,整体结构变得更加致密,RM中的Na含量从10.44 wt%降至0.86 wt%。用稳定化材料处理后,低碱度RM的力学强度得到显著提高,复合矿渣的稳定化效果最佳。当部分替代率为12%时,28 d抗压强度为4.51 MPa。在水中浸泡一天一夜后,强度下降了24.3%,具有良好的稳定性。该研究发现强度增加主要归因于CaAlO等晶体物质以及填充孔隙和包裹颗粒的C-S-H等非晶体物质。该研究为RM稳定化提供了一种新方法,并促进了工业副产品的利用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d62/12250789/fbde151f88b9/materials-18-03140-g001.jpg

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