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用于生物医学植入物制造的聚己内酯基碳纳米管纳米复合材料的注塑成型模拟

Injection Molding Simulation of Polycaprolactone-Based Carbon Nanotube Nanocomposites for Biomedical Implant Manufacturing.

作者信息

Formas Krzysztof, Janusz Jarosław, Kurowska Anna, Benko Aleksandra, Piekarczyk Wojciech, Rajzer Izabella

机构信息

Department of Mechanical Engineering Fundamentals, Faculty of Mechanical Engineering and Computer Science, University of Bielsko-Biala, 43-309 Bielsko-Biala, Poland.

Department of Biomaterials and Composites, Faculty of Materials Science and Ceramics, AGH University of Krakow, al. A. Mickiewicza 30, 30-059 Kraków, Poland.

出版信息

Materials (Basel). 2025 Jul 6;18(13):3192. doi: 10.3390/ma18133192.

Abstract

This study consisted of the injection molding simulation of polycaprolactone (PCL)-based nanocomposites reinforced with multi-walled carbon nanotubes (MWCNTs) for biomedical implant manufacturing. The simulation was additionally supported by experimental validation. The influence of varying MWCNT concentrations (0.5%, 5%, and 10% by weight) on key injection molding parameters, i.e., melt flow behavior, pressure distribution, temperature profiles, and fiber orientation, was analyzed with SolidWorks Plastics software. The results proved the low CNT content (0.5 wt.%) to be endowed with stable filling times, complete mold cavity filling, and minimal frozen regions. Thus, this formulation produced defect-free modular filament sticks suitable for subsequent 3D printing. In contrast, higher CNT loadings (particularly 10 wt.%) led to longer fill times, incomplete cavity filling, and early solidification due to increased melt viscosity and thermal conductivity. Experimental molding trials with the 0.5 wt.% CNT composites confirmed the simulation findings. Following minor adjustments to processing parameters, high-quality, defect-free sticks were produced. Overall, the PCL/MWCNT composites with 0.5 wt.% nanotube content exhibited optimal injection molding performance and functional properties, supporting their application in modular, patient-specific biomedical 3D printing.

摘要

本研究包括用于生物医学植入物制造的、以聚己内酯(PCL)为基、用多壁碳纳米管(MWCNT)增强的纳米复合材料的注塑成型模拟。该模拟还得到了实验验证的支持。使用SolidWorks Plastics软件分析了不同MWCNT浓度(重量百分比为0.5%、5%和10%)对关键注塑成型参数的影响,即熔体流动行为、压力分布、温度曲线和纤维取向。结果证明,低CNT含量(0.5重量%)具有稳定的填充时间、完全填充模腔以及最小的冻结区域。因此,这种配方生产出了无缺陷的模块化丝状棒材,适合后续的3D打印。相比之下,较高的CNT含量(特别是10重量%)由于熔体粘度和热导率增加,导致填充时间延长、模腔填充不完全以及过早凝固。对0.5重量% CNT复合材料进行的实验成型试验证实了模拟结果。在对加工参数进行 minor 调整后,生产出了高质量、无缺陷的棒材。总体而言,纳米管含量为0.5重量%的PCL/MWCNT复合材料表现出最佳的注塑成型性能和功能特性,支持它们在模块化、针对患者的生物医学3D打印中的应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21ee/12250819/2b14aead987b/materials-18-03192-g001.jpg

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