Zhao Yuzhi, Li Jiaqun, Luo Ma, Han Haoze, Li Yaoyao, Xie Jiawang, Yan Jianfeng, Guo Heng
Department of Mechanical Engineering, Tsinghua University, Beijing 100084, People's Republic of China.
State Key Laboratory of Tribology in Advanced Equipment, Tsinghua University, Beijing 100084, People's Republic of China.
ACS Appl Mater Interfaces. 2025 Jul 16. doi: 10.1021/acsami.5c07670.
Flexible film materials are fundamental components of flexible electronics. High-precision patterning of metal on a flexible substrate is essential for device fabrication. Ultrafast laser processing offers unique advantages in precise flexible film patterning through its minimal thermal effect and high spatial resolution. However, current laser-based fabrication techniques face challenges in simultaneously controlling the ablation depth and maintaining substrate integrity. Herein, a femtosecond laser controllable ablation strategy is proposed for metal-polymer composite films that enables high-resolution patterning for tactile sensing applications. Theoretical analysis combining thermomechanical calculations and molecular dynamics simulations reveals that laser-induced stress serves as the dominant mechanism for silver layer removal. By controlling the laser fluence incident on the silver layer, selective ablation while maintaining substrate integrity is revealed. Based on the proposed strategy, high-performance flexible sensor arrays are fabricated, which are successfully integrated into a human-machine interaction system for real-time touch detection. This research advances the fundamental understanding of ultrafast laser ablation processing mechanisms and provides a reliable fabrication approach for flexible electronics and interactive systems.
柔性薄膜材料是柔性电子器件的基本组成部分。在柔性基板上对金属进行高精度图案化对于器件制造至关重要。超快激光加工通过其最小的热效应和高空间分辨率,在精确的柔性薄膜图案化方面具有独特优势。然而,当前基于激光的制造技术在同时控制烧蚀深度和保持基板完整性方面面临挑战。在此,提出了一种用于金属 - 聚合物复合薄膜的飞秒激光可控烧蚀策略,该策略能够实现用于触觉传感应用的高分辨率图案化。结合热机械计算和分子动力学模拟的理论分析表明,激光诱导应力是银层去除的主要机制。通过控制入射到银层上的激光能量密度,揭示了在保持基板完整性的同时进行选择性烧蚀的方法。基于所提出的策略,制造了高性能柔性传感器阵列,并成功集成到人机交互系统中用于实时触摸检测。这项研究推进了对超快激光烧蚀加工机制的基本理解,并为柔性电子器件和交互系统提供了一种可靠的制造方法。