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由磁弹性纤维网络固定液态金属实现的高性能、应变稳定电磁屏蔽材料。

High-Performance, Strain-Stable Electromagnetic Shielding Materials Enabled by Magnetic Elastic Fiber Networks Pinning Liquid Metal.

作者信息

Zhang Qi, Wu Yuanzhao, Bao Xilai, Li Shengbin, Zhuang Xueheng, He Zidong, Liu Jinyun, Zhang Wuxu, Li Shiying, Xu Feng, Zeng Chuibin, Hu Chao, Man Qikui, Shang Jie, Liu Yiwei, Li Run-Wei

机构信息

Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, P. R. China.

College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.

出版信息

Adv Sci (Weinh). 2025 Jul 18:e10078. doi: 10.1002/advs.202510078.

Abstract

Stretchable electromagnetic interference (EMI) shielding materials are critical for the reliability of wearable electronic devices in complex electromagnetic environments. However, achieving compatibility between ultra-thinness, high shielding efficiency (SE), and excellent dynamic stability remains a major challenge in this field. Here, an ultrathin elastic EMI shielding film (TPU/Fe-LM) is developed by leveraging the magnetoelectric synergy effect and a pinning-interlocking mechanism between ferromagnetic elastic nanofiber networks and the embedded liquid metal (LM), achieving high EMI SE and excellent strain stability. The ultrathin film, with a thickness of 85 µm, exhibits an average EMI SE exceeding 70 dB across a broad frequency range of 0.1 MHz to 40 GHz, with only a 2.59% variation under 100% tensile strain. This superb EMI SE per unit thickness (SSE = 1225 dB mm @ 100% strain) ranks among the highest reported for stretchable EMI shielding films, highlighting the exceptional application potential. As a proof of concept, the EMI shielding film is integrated into a stretchable capacitive strain sensor for dynamic and static force sensing, achieving a 50-fold enhancement in angle resolution for robotic motion monitoring. This research paves the way for stretchable EMI shielding materials and offers valuable guidance for enhancing electromagnetic protection in wearable electronics.

摘要

可拉伸电磁干扰(EMI)屏蔽材料对于复杂电磁环境中可穿戴电子设备的可靠性至关重要。然而,在超薄、高屏蔽效率(SE)和出色的动态稳定性之间实现兼容性仍然是该领域的一项重大挑战。在此,通过利用磁电协同效应以及铁磁弹性纳米纤维网络与嵌入式液态金属(LM)之间的钉扎-联锁机制,开发出一种超薄弹性EMI屏蔽膜(TPU/Fe-LM),实现了高EMI SE和出色的应变稳定性。该超薄膜厚度为85 µm,在0.1 MHz至40 GHz的宽频率范围内平均EMI SE超过70 dB,在100%拉伸应变下变化仅为2.59%。这种每单位厚度的出色EMI SE(SSE = 1225 dB·mm @ 100%应变)在已报道的可拉伸EMI屏蔽膜中名列前茅,突出了其卓越的应用潜力。作为概念验证,该EMI屏蔽膜被集成到一个可拉伸电容式应变传感器中用于动态和静态力传感,在机器人运动监测的角度分辨率方面实现了50倍的提升。这项研究为可拉伸EMI屏蔽材料铺平了道路,并为增强可穿戴电子产品中的电磁保护提供了有价值的指导。

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