Boström Hanna L B, Kholina Yevheniia, Simonov Arkadiy
Department of Chemistry, Stockholm University Svante Arrhenius väg 16C SE-106 91 Stockholm Sweden
Wallenberg Initiative Materials Science for Sustainability, Department of Chemistry, Stockholm University SE-114 18 Stockholm Sweden.
J Mater Chem C Mater. 2025 Jul 10;13(30):15290-15302. doi: 10.1039/d5tc01760b. eCollection 2025 Jul 31.
The metal-cyanide frameworks known as Prussian blue analogues display a suite of diverse and tuneable properties. In particular, they are often highly susceptible to modification by external stimuli, such as temperature, pressure, radiation, adsorbed guests, or electric/magnetic fields. This can lead to rare and intriguing phenomena-including humidity-induced magnetism, electrochromism, or light-switchable electronic bistability-which enable a wide range of potential applications. The present article briefly surveys the stimuli-responsive behaviour of Prussian blue analogues, including spin crossover, charge transfer, chromism, conductivity, magnetism, and strain. Throughout, areas with potential for future developments are highlighted.
被称为普鲁士蓝类似物的金属氰化物框架具有一系列多样且可调节的性质。特别是，它们通常极易受到外部刺激的影响，如温度、压力、辐射、吸附客体或电场/磁场。这可能导致罕见且引人入胜的现象，包括湿度诱导的磁性、电致变色或光控电子双稳态，从而实现广泛的潜在应用。本文简要综述了普鲁士蓝类似物的刺激响应行为，包括自旋交叉、电荷转移、变色、导电性、磁性和应变。文中始终突出了具有未来发展潜力的领域。
