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用于可持续3D打印的松果衍生生物碳-聚乳酸复合材料

Pinecone-Derived Biocarbon-Polylactic Acid Composites for Sustainable 3D Printing.

作者信息

Arora Nishtha, Yadav Omvesh, Dua Sachin, Singh Shailesh Kumar, Palla Venkata Chandra Sekhar, Senthilkumar Thangaraj

机构信息

Polymeric Materials Area, Chemical and Material Sciences Division, CSIR-Indian Institute of Petroleum, Dehradun 248005, India.

Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India.

出版信息

ACS Appl Bio Mater. 2025 Jul 21. doi: 10.1021/acsabm.5c00971.

Abstract

To address the escalating need for sustainable manufacturing, the integration of biomass-sourced carbon particles with biodegradable polymers offers a promising and innovative solution. This approach not only tackles environmental dilemmas but also drives material science forward, providing a promising pathway for eco-friendly progress. The present study focuses on developing pinecone-derived biocarbon (PCAC)-infused polylactic acid (PLA) composites for fused deposition modeling (FDM)-based additive manufacturing applications. An in-depth investigation was carried out on the developed composites, wherein the proportion of PCAC was modulated across a range of 0.025 to 0.100 wt %, enabling a comprehensive evaluation of composition-dependent characteristics. The morphological and optical analysis confirmed the consistent and homogeneous dispersion of PCAC throughout the PLA framework. A notable enhancement in mechanical performance was observed, with tensile strength experiencing a 60% increase at an optimal PCAC loading of 0.075 wt %. Beyond advancing sustainable initiatives, the research highlights the potential of PLA-PCAC biocomposites as a sustainable and effective substitute for conventional 3D printing materials. The ability of PLA-biocarbon composites in the form of spoons and glass to sustain the 3D printing process is demonstrated, and the enzymatic biodegradability of these polymeric composites is evaluated.

摘要

为满足对可持续制造不断增长的需求,将生物质来源的碳颗粒与可生物降解聚合物相结合提供了一种有前景的创新解决方案。这种方法不仅解决了环境难题,还推动了材料科学的发展,为环保进步提供了一条有前景的途径。本研究专注于开发用于基于熔融沉积建模(FDM)的增材制造应用的、含有松果衍生生物碳(PCAC)的聚乳酸(PLA)复合材料。对所开发的复合材料进行了深入研究,其中PCAC的比例在0.025至0.100 wt%的范围内进行调节,以便全面评估与组成相关的特性。形态学和光学分析证实了PCAC在整个PLA框架中均匀一致的分散。观察到机械性能有显著提高,在PCAC最佳负载量为0.075 wt%时,拉伸强度提高了60%。除了推进可持续发展举措外,该研究还突出了PLA-PCAC生物复合材料作为传统3D打印材料的可持续且有效替代品的潜力。展示了勺子和杯子形式的PLA-生物碳复合材料维持3D打印过程的能力,并评估了这些聚合物复合材料的酶促生物降解性。

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