Xu Qinghu, Liu Shuchang, Qian Junjie, Xu Rongsheng, Ma Wei
School of Civil Engineering, Anhui Jianzhu University, Hefei, 230009, China.
Sci Rep. 2025 Jul 21;15(1):26438. doi: 10.1038/s41598-025-11384-1.
The use of copper slag instead of part of the slag to prepare alkali-activated cementitious materials can achieve the resource utilisation of copper slag, but alkali-activated copper slag-slag composite cementitious materials have the disadvantages of high shrinkage and low flexural strength, which limit their application in practical engineering. In order to improve its performance, this study used glass fiber, polypropylene fiber, steel fiber at 0.2%, 0.4%, 0.6%, 0.8%, 1.0% by volume admixture into alkali-activated copper slag-slag composite cementitious materials, respectively, to explore the effect of fiber on the drying shrinkage and mechanical properties of alkali-activated copper slag-slag composite cementitious materials. The test results show that the addition of fibers can compensate the drying shrinkage of AAMs and improve their mechanical properties. 1.0% of GF and SF can compensate the drying shrinkage of 17.5% and 27.3%, and PPF can also inhibit the drying shrinkage of the material, but the drying shrinkage will be exacerbated when the dosage is more than 0.8%. The addition of fibers does not have a significant effect on the compressive strength, but significantly improves the flexural strength of the material. When the dosage of GF, PPF and SF reaches 0.6%, 0.8% and 1.0% respectively, the flexural strength of the specimen at 28d is increased by 7.9%, 19.86% and 61.66% compared with that of the blank control group, respectively. Through microstructural analysis, it was found that the fibers formed a mesh structure in the material, which effectively inhibited the development of cracks and improved the toughness of the material. This study provides a theoretical basis and practical guidance for the optimization of the properties of alkali-activated copper slag-slag composite cementitious materials.
使用铜渣替代部分矿渣制备碱激发胶凝材料可实现铜渣的资源利用,但碱激发铜渣 - 矿渣复合胶凝材料存在收缩率高和抗折强度低的缺点,这限制了它们在实际工程中的应用。为了改善其性能,本研究分别将体积掺量为0.2%、0.4%、0.6%、0.8%、1.0%的玻璃纤维、聚丙烯纤维、钢纤维掺入碱激发铜渣 - 矿渣复合胶凝材料中,以探究纤维对碱激发铜渣 - 矿渣复合胶凝材料干燥收缩和力学性能的影响。试验结果表明,纤维的加入可补偿碱激发材料的干燥收缩并改善其力学性能。1.0%的玻璃纤维和钢纤维可分别补偿17.5%和27.3%的干燥收缩,聚丙烯纤维也可抑制材料的干燥收缩,但当掺量超过0.8%时干燥收缩会加剧。纤维的加入对抗压强度影响不显著,但显著提高了材料的抗折强度。当玻璃纤维、聚丙烯纤维和钢纤维的掺量分别达到0.6%、0.8%和1.0%时,与空白对照组相比,28d龄期试件的抗折强度分别提高了7.9%、19.86%和61.66%。通过微观结构分析发现,纤维在材料中形成了网状结构,有效抑制了裂缝的发展并提高了材料的韧性。本研究为碱激发铜渣 - 矿渣复合胶凝材料性能的优化提供了理论依据和实际指导。