Zanotto Federica, Sirico Alice, Balbo Andrea, Bernardi Patrizia, Merchiori Sebastiano, Grassi Vincenzo, Belletti Beatrice, Monticelli Cecilia
Department of Engineering, Corrosion and Metallurgy Study Centre "A. Daccò", University of Ferrara, Via G. Saragat 4A, 44122 Ferrara, Italy.
Department of Engineering and Architecture, University of Parma, Parco Area delle Scienze 181/A, 43124 Parma, Italy.
Materials (Basel). 2025 Jul 17;18(14):3361. doi: 10.3390/ma18143361.
Recycling plastics waste into concrete represents one of the possible approaches for its valorization, offering both economic and environmental benefits. Although numerous studies have explored the mechanical properties of concrete with plastics waste, its durability performance remains largely unexplored. In this context, this study aims to assess the electrochemical behavior of rebars embedded in reinforced concrete modified by partially replacing natural aggregates with recycled plastics, comparing their behavior to that of conventional concrete. The corrosion of reinforcing steel bars was evaluated by wet and dry cycles (w/d) in calcium chloride solutions, monitoring corrosion potential and potentiostatic polarization resistance, and recording electrochemical impedance spectroscopy (EIS) and polarization curves. In addition, the chloride diffusion tendency and the mechanical performances were assessed in unreinforced samples. The findings indicate that in environments with lower chloride concentrations, concrete with plastic granules provides good protection against rebar corrosion. Although the mechanical results of the studied mixes confirmed that incorporating plastic granules as aggregates in the concrete matrix causes a reduction in compressive strength, as known in the literature, the modified concrete also exhibits improved post-cracking behavior, resulting in enhanced ductility and fracture toughness.
将塑料垃圾回收再利用制成混凝土是实现其价值的一种可行方法,具有经济和环境双重效益。尽管众多研究探讨了含有塑料垃圾的混凝土的力学性能,但其耐久性表现仍 largely 未被探索。在此背景下,本研究旨在评估用回收塑料部分替代天然骨料的钢筋混凝土中钢筋的电化学行为,并将其行为与传统混凝土的行为进行比较。通过在氯化钙溶液中进行干湿循环(w/d)来评估钢筋的腐蚀情况,监测腐蚀电位和恒电位极化电阻,并记录电化学阻抗谱(EIS)和极化曲线。此外,还对未配筋样品的氯离子扩散趋势和力学性能进行了评估。研究结果表明,在氯化物浓度较低的环境中,含有塑料颗粒的混凝土能为钢筋腐蚀提供良好的防护。尽管所研究混合料的力学结果证实,如文献中所述,在混凝土基体中掺入塑料颗粒作为骨料会导致抗压强度降低,但改性混凝土在开裂后的性能也有所改善,从而提高了延性和断裂韧性。