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暴露于氯化钙循环环境下的再生塑料骨料混凝土中钢筋腐蚀的试验研究

Experimental Investigation of Steel Bar Corrosion in Recycled Plastic Aggregate Concrete Exposed to Calcium Chloride Cycles.

作者信息

Zanotto Federica, Sirico Alice, Balbo Andrea, Bernardi Patrizia, Merchiori Sebastiano, Grassi Vincenzo, Belletti Beatrice, Monticelli Cecilia

机构信息

Department of Engineering, Corrosion and Metallurgy Study Centre "A. Daccò", University of Ferrara, Via G. Saragat 4A, 44122 Ferrara, Italy.

Department of Engineering and Architecture, University of Parma, Parco Area delle Scienze 181/A, 43124 Parma, Italy.

出版信息

Materials (Basel). 2025 Jul 17;18(14):3361. doi: 10.3390/ma18143361.

DOI:10.3390/ma18143361
PMID:40731572
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12297927/
Abstract

Recycling plastics waste into concrete represents one of the possible approaches for its valorization, offering both economic and environmental benefits. Although numerous studies have explored the mechanical properties of concrete with plastics waste, its durability performance remains largely unexplored. In this context, this study aims to assess the electrochemical behavior of rebars embedded in reinforced concrete modified by partially replacing natural aggregates with recycled plastics, comparing their behavior to that of conventional concrete. The corrosion of reinforcing steel bars was evaluated by wet and dry cycles (w/d) in calcium chloride solutions, monitoring corrosion potential and potentiostatic polarization resistance, and recording electrochemical impedance spectroscopy (EIS) and polarization curves. In addition, the chloride diffusion tendency and the mechanical performances were assessed in unreinforced samples. The findings indicate that in environments with lower chloride concentrations, concrete with plastic granules provides good protection against rebar corrosion. Although the mechanical results of the studied mixes confirmed that incorporating plastic granules as aggregates in the concrete matrix causes a reduction in compressive strength, as known in the literature, the modified concrete also exhibits improved post-cracking behavior, resulting in enhanced ductility and fracture toughness.

摘要

将塑料垃圾回收再利用制成混凝土是实现其价值的一种可行方法,具有经济和环境双重效益。尽管众多研究探讨了含有塑料垃圾的混凝土的力学性能,但其耐久性表现仍 largely 未被探索。在此背景下,本研究旨在评估用回收塑料部分替代天然骨料的钢筋混凝土中钢筋的电化学行为,并将其行为与传统混凝土的行为进行比较。通过在氯化钙溶液中进行干湿循环(w/d)来评估钢筋的腐蚀情况,监测腐蚀电位和恒电位极化电阻,并记录电化学阻抗谱(EIS)和极化曲线。此外,还对未配筋样品的氯离子扩散趋势和力学性能进行了评估。研究结果表明,在氯化物浓度较低的环境中,含有塑料颗粒的混凝土能为钢筋腐蚀提供良好的防护。尽管所研究混合料的力学结果证实,如文献中所述,在混凝土基体中掺入塑料颗粒作为骨料会导致抗压强度降低,但改性混凝土在开裂后的性能也有所改善,从而提高了延性和断裂韧性。

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本文引用的文献

1
Fresh and hardened properties of concrete containing different forms of plastic waste - A review.含有不同形式塑料废弃物的混凝土的新鲜和硬化性能——综述。
Waste Manag. 2020 Jul 15;113:157-175. doi: 10.1016/j.wasman.2020.05.048. Epub 2020 Jun 10.
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Properties of lightweight aggregate concrete prepared with PVC granules derived from scraped PVC pipes.由废弃聚氯乙烯(PVC)管材制成的PVC颗粒制备的轻集料混凝土的性能
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Use of recycled plastic in concrete: a review.
再生塑料在混凝土中的应用:综述
Waste Manag. 2008;28(10):1835-52. doi: 10.1016/j.wasman.2007.09.011. Epub 2007 Nov 5.
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Use of waste plastic in concrete mixture as aggregate replacement.在混凝土混合物中使用废塑料作为骨料替代品。
Waste Manag. 2008 Nov;28(11):2041-7. doi: 10.1016/j.wasman.2007.08.023. Epub 2007 Oct 10.
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Valorization of post-consumer waste plastic in cementitious concrete composites.消费后废塑料在水泥基混凝土复合材料中的增值利用。
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